Identifikasi Logam Berat dalam Biji Jagung Manis dan Kedelai pada Transisi Sistem Pertanian Organik

https://doi.org/10.22146/agritech.24739

Sapto Priyadi(1*), Soelistijono Soelistijono(2), Setie Harieni(3), Kusriani Prasetyowati(4)

(1) Program Studi Agroteknologi, Fakultas Pertanian, Universitas Tunas Pembangunan, Jl. Balekambang Lor No. 1 Surakarta 57139
(2) Program Studi Agroteknologi, Fakultas Pertanian, Universitas Tunas Pembangunan, Jl. Balekambang Lor No. 1 Surakarta 57139
(3) Program Studi Agroteknologi, Fakultas Pertanian, Universitas Tunas Pembangunan, Jl. Balekambang Lor No. 1 Surakarta 57139
(4) Program Studi Agribisnis, Fakultas Pertanian, Universitas Tunas Pembangunan Jl. Balekambang Lor No. 1 Surakarta 57139
(*) Corresponding Author

Abstract


Heavy metal contaminants in land agriculture are environmental problems, and they affect food safety, so there is a need for the research of Pb, Cd and Cu decrease absorption by plants using organic chelating agent, i.e. substance of humus (humic and fulvic acid) in the manure. The research was done with a completely block design, in Gagaksipat, Ngemplak, Boyolali; heavy metal analysis in manure, land and seeds used an atomic absorption spectrophotometer-flame (AAS Jena Contr AA 300, Germany). It was aimed to identify contaminants of Pb, Cd, and Cu in sweet corn and soybean seeds. The research treatments were doses of cow manure: 15, 20, 25, 30, 35, 40, 45 and 50 kg per hectare. The results showed that the enrichment coefficient (EC) of Pb and Cu in sweet corn seeds had low accumulator plants categories; the EC of plumbum in soybean seeds had low accumulator plants categories, whereas the EC of copper soybean seeds had moderate accumulator plants categories; and the EC of cadmium in the sweet corn and soybeans seeds was undetectable. Exposures of Pb and Cd in corn sweet and soybean seeds were undetectable, while exposures of Cu in sweet corn and soybean seeds were 2.03 and 12.39 ppm, respectively. Contamination of Pb, Cd and Cu exposures in land after sweet corn harvested were 30.99; undetectable and 60.58 ppm, respectively. While Pb, Cd and Cu residues in land after soybean harvested were 33.24; undetectable and 56.26 ppm, respectively.

Keywords


Plumbum; cadmium; copper; manure, soybean

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References

Amer, S. (2012). As many scientist and enginer have discovered in recent years, the treatment of citrate-chelated metals may not be as complicated as some researchers original believed. www.polllutionenginering.com [Diunduh 28 Maret 2014].

Anonim (2005). Offical methode of analysis of the association of offical analytical chemist. Association of Analytical Chemist 17th edition Washington, D.C.

Ansari, A, R., Kazi A, T.G., Jamali A, M.K., Arain A, M.B., Wagan B, M.D., Nusrat Jalbani C, Afridi A, H.I. dan Abdul Qadir Shah A., A.Q. (2009). Variation in accumulation of heavy metals in different verities of sunflower seed oil with the aid of multivariate technique. Food Chemistry 115: 318–323.

Balia, R.L., Harlia, E., Denny dan Suryanto (2007). Keamanan pangan hasil ternak ditinjau dari cemaran logam berat. Fakultas Peternakan Universitas Padjadjaran. blogs.unpad.ac.id/roostitabalia/wp-content/. [30 Januari 2010].

Burke, R. A. (2013). Hazardous Materials Chemistry for Emergency Responders. 3th edition. CRC press Taylor and Francis Group, LLC. Books.Google. co.id. [diunduh 3 Mei 2014].

Charlena (2004). Pencemaran Logam Berat Timbal (Pb) dan Cadmium (Cd) Pada Sayur-Sayuran. Falsafah Sain, Program Pascasarjana/S3/Institut Pertanian Bogor. http://www.scribd.com/doc/. [30 Januari 2010].

Chiroma, T. M., Abdulkarim, B. I and Kefas, H. M. (2007). The impact of pesticide application on heavy metal (Cd, Pb and Cu) levels in spinach. Leonardo. Electronic Journal of Practices and Technologies 11: 117-122.

Drazic, G. and Mihailovic, N. (2005). Modification of cadmium toxicity in soybean seedlings by salicylic acid. Plant Science 168: 511-517.

Duressa, T.F. and Leta, S. (2015). Determination of levels of As, Cd, Cr, Hg and Pb in soils and some vegetables taken from river mojo water irrigated farmland at Koka Village, Oromia State, East Ethiopia. International Journal of Sciences: Basic and Applied Research, 21 (2): 352-372.

Gonzales, A.G. and Horrador, M.A. (2007). A Pratical guide to analytical methode validation, including measurement uncertainty and accuracy profiles. Trend in Analytical Chenmistry 26: 227-238.

Hou, J., Lu, R., Sun, M., Baig, S.A., Tang, T., Cheng, L. and Xu, X. (2012). Effect of heavy metals on the stabilization of mercury (II) by DTCR in desulfurization solutions. Journal of Hazardous Materials 217–218: 224–230.

Jolly, Y.N., Islam, A., and Akbar, S. (2013). Transfer of metals from soil to vegetables and possible health risk assessment. Springer Plus, 2:385.

Kisic, I., Jurisic, A., Mesic, H. and Mesic, S. (2011). Heavy metals uptake by aerial biomass and grain of soybean. Dalam Soybean - Biochemistry, Chemistry and Physiology. InTech, www.intechopen.com/ books/ advances. 642p. [diunduh 11 September 2013].

Kołodyńska, D. (2011). Chelating agent of a new generation as an alternative to conventional chelators for heavy metal ions removal from different waste waters. Dalam Ning, R.Y., Expanding Issues in Desalination. InTech, www.intechopen.com/books/ advances. 412p. [diunduh 11 September 2013].

Li, Q., Chai, L., Wang, Q., Yang, Z., Yan, H. dan Wang Y. (2010). Fast esterifikasi of spent grain for enhanced heavy metal ions adsorption. Bioresource Technology101: 3796-3799.

Mema, V. “V”. (2006). Identification of extraction methods for the production of humic acids from black liquor. Department of Process Engineering at the University of Stellenbosch. https://scholar.sun.ac.za [11 November 2015].

Mendoza-Co´zatl, D.G., Jobe, T.O., Hauser, F. dan Schroeder, J.I. (2011). Long-distance transport, vacuolar sequestration, tolerance, and transcriptional responses induced by cadmium and arsenic. Plant Biology 14: 554–562.

Miretzky, P., Saralegui, A. and Cirelli, A. F. (2006). Simultaneous heavy metal removal mechanism by dead macrophytes. Chemosphere 62: 247–254.

Oti, W.O. (2015). Bioaccumulation factors and pollution indices of heavy metals in selected fruits and vegetables from a derelict mine and their associated health implications. International Journal of Environment and Sustainability, 4 (1): 15-23

Pettit, R.E. (2012). Organic matter, humus, humate, humic acid, fulvic acid and humin: Their importance in soil fertility and plant health. Emeritus Associate Professor Texas A&M University, www.humates.com [22 April 2012].

Prasetiyono, E. (2013). Studi perbandingan kompos dari daun tumbuhan dengan C/N rasio berbeda terhadap adsorpsi logam berat timah hitam (Pb) pada media budidaya ikan. Akuatik Jurnal Sumberdaya Perairan 7 (2).

Priyadi, S., Darmaji, P., Santoso, U., dan Hastuti, P. (2013). Khelasi plumbum (Pb) dan cadmium (Cd) menggunakan asam sitrat pada biji kedelai. Jurnal Agritech 33 (4), Fakultas Teknologi Pertanian Universitas Gadjah Mada.

-------------- (2014).Distribusi plumbum, cadmium pada biji kedelai dan deprotonasi gugus fungsional karboksil asam sitrat dalam khelasi. Jurnal Agritech 34 (4), Fakultas Teknologi Pertanian Universitas Gadjah Mada.

Sarosa, W. J. (2010). Super kimia. Kawah Media Jakarta Selatan. Books.google.co.id. [diunduh 23 Maret 2014].

Schnitzer, M., Khan, S.U. (1978). Soil Organic Matter. New York: Elselvier Scientific Publishing Company.

Susiati, H., S.B.S. Yarianto, Arman L.A. dan Menri, Y. (2008). Kandungan logam berat (Cu, Cr, Zn, dan Fe) pada terumbukarang di perairan Pulau Panjang, Jepara. Jurnal Batan.go.id. Pusat Pengembangan Energi Nuklir – BATAN [diunduh 2 Juli 2016].

Ullah, S. (2007). Chemically Enhanced Phytoextraction of Lead from Contaminated Soil. Institute of Soil and Environment Sciences University of Agriculture, Faisalabad Pakistan.

Varrault, G., Camel, V., and Bermond, A. (2000). Adsorption of trace metal ion onto humic acid, p. 587-588, in: Proceedings 10th International Meeting of the International-Humic Substances Society.

Winter, M. (2012). WebElement: The periodic table on the web. The University of Sheffield England and WebElement Ltd, UK. Books.google.co.id. [diunduh 22 Mei 2014].

Yong, Z., Bo-Han, L., Qing-Ru, Z., Min, Z., and Ming, L. (2008). Surfactant linear alkylbenzene sulfonate effect on soil Cd fractions and Cd distribution in soybean plant in pot experiment. Pedosphere 18 (2): 242-247.

Zheljazkov,V.D., Craker, L.E dan Xing, B. (2006). Effects of Cd, Pb, and Cu on growth and essential oil contents in dill, peppermint, and basil. Environmental and Experimental Botany58: 9 –16.



DOI: https://doi.org/10.22146/agritech.24739

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