* Corresponding Author
Pemurnian Produk Mono-Diasilgliserol (MDAG) Hasil Gliserolisis Kimia dengan Metode Demulsifikasi Krim
https://doi.org/10.22146/agritech.48779 Satiti Kawuri Putri(1*), Purwiyatno Hariyadi(2), Mursalin Mursalin(3), Nuri Andarwulan(4)
(1) IPB University
(2) Southeast Asian Food and Agricultural Science and Technology (SEAFAST) Center, Institut Pertanian Bogor, Dramaga Bogor 16680
(3) Fakultas Teknologi Pertanian, Universitas Jambi, Jl. Tribrata, Desa Pondok Meja Km. 11, Mestong Jambi 36364
(4) Southeast Asian Food and Agricultural Science and Technology (SEAFAST) Center, Institut Pertanian Bogor, Dramaga Bogor 16680
(*) Corresponding Author
Abstract
Cream demulsification is one of the purification method for separating the glycerol residue contained as emulsion with MDAG’s product. This method could be used to break emulsion system by adding electrolyte solution. This research aims to compare the performance of calcium chloride and calcium nitrate as electrolyte solution that is used in the process of cream demulsification. MDAG used was Fully Hydrogenated Palm Kernel Oil (FHPKO) from glycerolysis process. Based on student t-test, there was no significant difference (p>0,05) detected between the products of cream demulsification method using calcium nitrate and calcium chloride as electrolyte solution. It was discovered that calcium nitrate reduced residual glycerol from 11,69±0.88% to 0,57±0,07%; with characteristics of MDAG’s products were free fatty acid (ALB) of 8,51±0,94%, monoacylglycerol (MAG) of 31,53±3,27%, diacylglycerol (DAG) of 19,46±0,52%, triacylglycerol (TAG) of 39,93±4,66% and yield of 81,00±3,61%.respectively. In other hand, calcium chloride reduced residual glycerol from 11,69±0,88% to 0,64±0,06%; with characteristics of MDAG’s products were ALB of 8,91±0,71%, MAG of 9,79±1,97%, DAG of 19,16±0,53%, TAG of 41,49±3,24% and yield of 80,00±4,00%, respectively. Therefore, calcium nitrate can be to replace calcium chloride as electrolyte solution in cream demulsification method, especially in reducing the glycerol residue.
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Agustina, L. C. (2019). Perubahan Komposisi Fraksi Asilgliserol selama Sintesis Mono-Diasilgliserol dari Stearin Sawit dengan Metode Gliserolisis Skala Pilot Plant. Bogor: Institut Pertanian Bogor.
AOAC. (2003). Association of official analytical chemist. Official methods of analysis. Washington DC (US), AOAC International.
BSN. (2018). Badan Standardisasi Nasional. ISO 6883:2017 Animal and Vegetable Fats and Oils – Determination of Conventional Mass per Volume (Litre Weight in Air), Jakarta.
Chen, L. (2015). Emulsifiers as Food Texture Modifiers. Modifying Food Texture, (pp 27-49).
Codex. (2017). Codex Allimentarius. CODEX STAN 210-1999. Codex Standard for Names Vegetable Oils, Roma.
Faergemant, M. & Krog, N., (2006). Interactions of Emulsifiers with Other Components in Foods. In Ingredient Interactions Effects on Food Quality (2nd ed.). (pp. 389-419).
Gadzuric, S., Vranes, M., & Dozic, S., (2010). Electrical Conductivity and Phase Transitions of Calcium Nitrate + Ammonium Nitrate + Water Mixtures. Journal of Chemical and Engineering Data. 55: 1990-1993.
Kellens, M., & Greyt, WD., (2016). 3-MCPD and GE. A New Challenge. https//www.omagazine.com [Agustus 2018].
Laksana, AJ. (2016). Penggandaan Skala Produksi Mono dan Diasilgliserol (MDAG) Berbasis Sawit dengan Metode Gliserolisis. Institut Pertanian Bogor.
Larsen, JC., (2009). ILSI Europe Report Series: 3-MCPD Ester in Food Products. Int Life Sci Inst.
Mardaweni, R., Setyaningsih, D., & Rusli, MS., (2017). Pemurnian Mono-Diasilgliserol Hasil Esterifikasi Palm Fatty Acid Distillate dan Gliserol dengan Ekstraksi Pelarut-Saponifikasi dan Distilasi Molekuler. Jurnal Teknologi Industri Pertanian, 27(2): 192-199.
McClements, DJ., (2015). Food Emulsions Principles, Practices and Techniques (3rd ed.) CRC Press.
Makhtar, NA., (2010). Effect of PH and Glycerol Waste Amount on the Glycerol Recovery. University Malaysia Pahang.
Moonen, H., & Bas, H., (2004). Mono-and Dyglycerides: Emulsifiers in Food Technology. (Whitehurst RJ, ed). Oxford (GB): Blackwell Scientific.
Moonen, H., & Bas, H., (2015). Mono and Diglycerides. In Emulsifiers in Food Technology. John Wiley & Sons, Ltd. UK.
Moura, JMLN., Campbel, K., Mahfuz, A., Jung, S., Glatz, CE., & Johnson, L., (2008). Enzyme-Assisted Aqueous Extraction of Oil and Protein from Soybeans and Cream De-emulsification. Journal of the American Oil Chemist Society, 85: 985-995. http://doi.org/10.1007/s11746-008-1282-2.
Moura, JMLN., Mourer, D., Jung, S., & Johnson, LA., (2011a). Integrated Countercurrent Two-Stage Extraction and Cream Demulsification in Enzyme-Assisted Aqueous Extraction of Soybeans. Journal of the American Oil Chemist Society, 88: 1045-1051. http://doi.org/10.1007/s11746-011-1759-2.
Moura, JMLN., Mourer, D., Jung, S., & Johnson, LA., (2011b). Pilot-Plant Proof-of-Concept for Integrated, Countercurrent, Two-Stage, Enzyme-Assisted Aqueous Extraction of Soybeans. Journal of the American Oil Chemist Society, 88: 1649-1658. http://doi.org/10.1007/s11746-011-1831-y.
Mujdalipah, S., Sasmita, AH., Amalia, IK., & Suryani, A., (2016). Separatiom of Glycerolysis Product Using Hexane. International Conference on Innovation in Engineering and Vocational Education, 128.
Mursalin., Lavlinesia., & Yernisa., (2017a). Aplikasi Teknik Demulsifikasi Pembentukan Krim dalam Pemurnian MDAG yang Diproduksi Secara Gliserolisis. Jurnal Ilmiah Ilmu Terapan Universitas Jambi, 1(2):170-177.
Mursalin., Sahrial.,& Wulandari, N., (2017b). Efektivitas NaCl dan CaCl2 dalam Memurnikan MDAG dengan Metode Creaming Demulsification Technique. Prosiding Seminar Nasional FKPT-TPI 2017. Kendari, Indonesia.
O’Brien, RD., (2009). Fats and Oils: Formulating and Processing for Applications, Florida (USA). CRC Press.
Rachmawati, D. (2017). Sintesis Mono-Diasilgliserol dari Refined Bleached Deodorized Palm Oildengan Metode Gliserolisis Skala Laboratorium. Institut Pertanian Bogor.
Rarokar, NR., Menghani, S., Kerzare, D., & Khedekar, PB., (2017). Progress in Synthesis of Monoglycerides for Use in Food and Pharmaceuticals. Journal of Food and Pharmaceutical Sciences, 2472-0542.
Rossi, P., Grosso, NR., Pramparo, MC., & Nepote, V., (2012). Fraction and Concentration of Omega-3 by Molecular Distillation. Eicosapentaenoic Acid: Sources Health Effects and Role in Disease Prevention, 177-203.
Rumondang, I., Setyaningsih, D., & Hermanda, A., (2016). Sintesis Mono-Diasilgliserol Berbasis Gliserol dan Palm Fatty Acid Distillate. Jurnal Kimia dan Kemasan, 38(1) : 1-6.
Saifuddin, N., & Refal, H., (2014). Separation of Water From very Stable Water-in-Oil Emulsions Using Microwave Radiation with Presence of Inorganic Salts. International Journal of Chemistry, 35(1): 1512-1521.
Sanchez, E., Castano, CP., & Bolanos, G., (2018). Purification of Monoglycerides from Palm Stearin by Liquid-Liquid Extraction with Aqueous Ethanol. Journal of the American Oil Chemist Society, 95: 217-228.
Sari, DK., & Lestari, RSD., (2015). Pengaruh Waktu dan Kecepatan Pengadukan terhadap Emulsi Minyak Biji Matahari (Helianthus annuus L.) dan Air. Jurnal Integrasi Proses, 5(3): 155-159.
Setyaningsih, D., Bashir, BA., Silalahi, VHY., Muna, N., (2016). Purification of Mono-Diacylglycerol Through Saponification and Solvent Extraction. International Journal Environment and Bioenergy, 11(1) : 1-11.
Silsia, D., Surawan, FED., Meiriska, I., (2017). Karakteristik Emulsifier Mono dan Diasilgliserol (MDAG) dari Crude Palm Oil (CPO) yang Berasal dari Fat Pit in Various Concentration of NaOH Catalyst. Jurnal Teknologi dan Industri Pertanian Indonesia, 9(2): 82-88.
Triana, RN. (2014). Sintesis Mono dan Diasilgliserol (MDAG) dari Fully Hydrogenated Palm Kernel Oil (FHPKO) dengan Metode Gliserolisis. Institut Pertanian Bogor.
Uhlig, BA., & Wissemeier, AH., (2000). Reduction of Non-Ionic Surfactant Phytotoxicity by Divalent Cations. Crop Protection, 19: 13-19.
Xia, L., Ying, XG., & Wei, S., (2010). Salt-Assisted Microwave Demulsification. Lianing University. Taylor and Francis Inc, China.
Zhang, Z., Ma, X., Wang, Y., Yan, R., & Liu, M., (2014). Production of Monoacylglycerols from Fully Hydrogenated Palm Oil Catalyzed by Hydrotalcite Loaded with K2CO3. Chemical Engineering Communications, http://doi.org/10.1080/00986445.2013.853294. DOI: https://doi.org/10.22146/agritech.48779
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