The Effect of NaOH Concentration on Silica Leaching Process from Rice Husk Ash in South Sulawesi Province, Indonesia

https://doi.org/10.22146/jrekpros.81242

Herlina Rahim(1), Gyan Prameswara(2*), Muh. Irfan Wijaya Gusmadi(3), Jamaluddin Jamaluddin(4)

(1) Politeknik ATI Makassar
(2) Politeknik ATI Makassar
(3) Politeknik ATI Makassar
(4) PT Tala Salapang Agro
(*) Corresponding Author

Abstract


The issue of waste and raw material sources has become common in the processing industry. The ideal solution is to use waste as a substitute for primary material. The processing of rice husk waste for silica extraction can aid in resolving the issue of solid waste accumulation in the agricultural industry. The extraction process begins with burning and ashing the husk waste to increase the silica content. At 750 oC, the silica content increased to 88.06%. The leaching process was carried out to dissolve Si, and observe the behavior of other major elements, such as K, Ca, and P, from rice husk ash. Leaching was carried out in a 3-neck flask with external heating. The effect of the concentration of NaOH solution on elements recovery was studied in this experiment. The highest recovery of Si, K, Ca, and P reached 89.94%, 89.04%, 61.37%, and 78.61%, respectively, at 3 N NaOH concentration, 120 minutes, 300 rpm, and 10% S/L ratio. There was also a precipitate of Na3PO4 formed in the product solution after being left for 24 hours. This provides insight into the decantation process before precipitation using Al(OH)3 in zeolite production.


Keywords


effect of concentration; leaching; rice husk ash

Full Text:

PDF


References

Alshatwi AA, Athinarayanan J, Periasamy VS. 2022. Simultaneous fabrication of carbon microspheres, lignin/silica nanohybrids, and cellulose nanostructures from rice husk. Biomass Conversion and Biorefinery. (0123456789):20–25. doi:10.1007/s13399-022-03158-w.

Badan Pusat Statistik. 2021. Luas panen dan produksi padi di Indonesia 2021 (angka sementara). https://www.bps.go.i d/.

Bakar RA, Yahya R, Gan SN. 2016. Production of high purity amorphous silica from rice husk. Procedia Chemistry. 19:189–195. doi:10.1016/j.proche.2016.03.092.

Chandrasekhar S, Satyanarayana KG, Pramada PN, Raghavan P. 2003. Review processing, properties and applications of reactive silica from rice husk—an overview. Journal of Materials Science. 38(2):3159–3168. doi:https://doi.org/10.1023/A:1025157114800.

Fernandes IJ, Calheiro D, Sánchez FA, Camacho ALD, De Campos Rocha TLA, Moraes CAM, De Sousa VC. 2017. Characterization of silica produced from rice husk ash: Comparison of purification and processing methods. Materials Research. 20:519–525. doi:10.1590/1980-5373-mr-2016-1043.

Ferreira JF, Filho JBdS, Liu X, Sandhu D. 2020. Spinach plants favor the absorption of K+ over Na+ regardless of salinity, and may benefit from Na+ when K+ is deficient in the soil. Plants. 9(4). doi:10.3390/plants9040507.

Istadi I, Prasetyo SA, Nugroho TS. 2015. Characterization of K2O/CaO-ZnO catalyst for transesterification of soybean oil to biodiesel. Procedia Environmental Sciences. 23:394–399. doi:10.1016/j.proenv.2015.01.056.

Kalapathy U, Proctor A, Shultz J. 2001. A simple method for production of pure silica from rice hull ash. Fuel and Energy Abstracts. 42(1):45. doi:10.1016/s0140-6701(01)804 87-2.

Liashenko A, Sknar Y, Hrydnieva T, Riabik P, Demchyshyna O, Plyasovskaya K. 2020. Studying the kinetics of extraction treatment of rice husk when obtaining silicon carbide. Eastern-European Journal of Enterprise Technologies. 1(6):25–31. doi:10.15587/1729-4061.2020.195881.

Ma X, Zhou B, Gao W, Qu Y, Wang L, Wang Z, Zhu Y. 2012. A recyclable method for production of pure silica from rice hull ash. Powder Technology. 217:497–501. doi:10.1016/j. powtec.2011.11.009.

Prameswara G, Tyassena FYP, Pasaribu M, Febryanzha IN. 2022a. Kinetics leaching mangan dari tipe ore limonite. Prosiding Seminar Nasional Teknologi Industri IX. Volume 1. Makassar: Politeknik ATI Makassar. p. 200–205.https://journal.atim.ac.id/index.php/prosiding/artic le/view/324.

Prameswara G, Tyassena FYP, Pasaribu M, Febryanzha IN. 2022b. Kinetika leaching Ni dan Fe dari bijih laterit tipe limonite Morowali. REACTOR: Journal of Research on Chemistry and Engineering. 3(2):57–62. http://reactor. poltekatipdg.ac.id/index.php/reactor/article/view/57.

Rivas A, Vera G, Palacios V, Rigail A, Cornejo Martínez MH. 2016. Characterization of rice husk and the crystallization process of amorphous silica from rice husk ash. Proceedings of the 14th LACCEI International MultiConference for Engineering, Education, and Technology: “Engineering Innovations for Global Sustainability”. January. Latin American and Caribbean Consortium of Engineering Institutions. doi:10.18687/LACCEI2016.1.1.093.

Santana Costa JA, Paranhos CM. 2018. Systematic evaluation of amorphous silica production from rice husk ashes. Journal of Cleaner Production. 192:688–697. doi:10.101 6/j.jclepro.2018.05.028.

Setyawan N, Hoerudin, Wulanawati A. 2019. Simple extraction of silica nanoparticles from rice husk using technical grade solvent: Effect of volume and concentration. IOP Conference Series: Earth and Environmental Science. 309(1). doi:10.1088/1755-1315/309/1/012032.

Steven S, Restiawaty E, Bindar Y. 2022. Operating variables on production of high purity bio-silica from rice hull ash by extraction process. Journal of Engineering and Technological Sciences. 54(3):220304. doi:10.5614/j.eng.tech nol.sci.2022.54.3.4.

Trisnawati I, Prameswara G, Rozana K, Petrus HTBM, Prasetya A, Mulyono P. 2020. Pelindian zirkonium dari tailing magnetik pasir zirkon hasil roasting menggunakan NaOH. Metalurgi. 35(3):83. doi:10.14203/metalurgi.v35i3.558.

Wang RC, Zhai YC, Ning ZQ, Ma PH. 2014. Kinetics of SiO2 leaching from Al2O3 extracted slag of fly ash with sodium hydroxide solution. Transactions of Nonferrous Metals Society of China (English Edition). 24(6):1928–1936. doi: 10.1016/S1003-6326(14)63273-8.



DOI: https://doi.org/10.22146/jrekpros.81242

Article Metrics

Abstract views : 451 | views : 227

Refbacks



Bookmark and Share


Copyright (c) 2023 The authors

Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Jurnal Rekayasa Proses  (print ISSN 1978-287X; online ISSN 2549-1490) is published by Chemical Engineering Department, Faculty of Engineering, Universitas Gadjah Mada. View website statistics.