Adsorption of Crystal Violet with Magnetic Graphene Oxide Nano Adsorbent Synthesized from  Schima wallichii  Wood

Danar Arifka Rahman; Mindriany Syafila; Qomarudin Helmy

doi:10.22146/ijc.80894

Adsorption of Crystal Violet with Magnetic Graphene Oxide Nano Adsorbent Synthesized from Schima wallichii Wood

https://doi.org/10.22146/ijc.80894

Danar Arifka Rahman^(1*), Mindriany Syafila⁽²⁾, Qomarudin Helmy⁽³⁾

(1) Study Program of Environmental Engineering, Department of Biology, Faculty of Science and Technology, Universitas Airlangga, Kampus C Mulyorejo, Surabaya 60115, Indonesia
(2) Water and Wastewater Engineering Expertise Group, Bandung Institute of Technology, Jl. Ganesha No. 10, Bandung 40132, West Java, Indonesia
(3) Water and Wastewater Engineering Expertise Group, Bandung Institute of Technology, Jl. Ganesha No. 10, Bandung 40132, West Java, Indonesia
(*) Corresponding Author

Abstract

The textile industry continues to experience production developments to reach a target for the country's economic development. The increase in production leads to an increase in the amount of waste generated. Dyes such as crystal violet (CV) in textile wastewater are toxic and difficult to remove by conventional treatment. Adsorption with nano adsorbent has been widely researched and developed to remove dyes in the environment because it has various advantages. Magnetic graphene oxide (GO-Fe₃O₄) as a006E adsorbent has been widely studied because it has a large surface area, strong chemical bonds and is easily separated from the aqueous phase. Puspa (Schima wallichii) wood has the potential to be used as a natural source of graphite. The characterization of the adsorbent was tested with FTIR, SEM-EDS, and BET. The equilibrium time for the adsorption process was 20 min, while the optimum adsorbent dose was 0.04 g. Adsorption isotherm and kinetics analysis showed that CV adsorption using MGO followed Langmuir and pseudo-second-order models, respectively. Thermodynamic studies displayed that the CV adsorption was endothermic and spontaneous. The results of this study suggested that the adsorption of CV using GO-Fe₃O₄ nano adsorbent from S. wallichii wood proceeds by chemisorption and physisorption.

Keywords

adsorption; crystal violet; dyes; nano adsorbent; wastewater

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References

[1] Suryawan, I.W.K., Helmy, Q., and Notodarmojo, S., 2018, Textile wastewater treatment: Colour and COD removal of reactive black-5 by ozonation, IOP Conf. Ser.: Earth Environ. Sci., 106 (1), 012102.

[2] Munagapati, V.S., and Kim, D.S., 2016, Adsorption of anionic azo dye Congo Red from aqueous solution by cationic modified orange peel powder, J. Mol. Liq., 220, 540–548.

[3] Sh. Gohr, M., Abd-Elhamid, A.I., El-Shanshory, A.A., and Soliman, H.M.A., 2022, Adsorption of cationic dyes onto chemically modified activated carbon: Kinetics and thermodynamic study, J. Mol. Liq., 346, 118227.

[4] Helmy, Q., Suryawan, I.W.K., and Notodarmojo, S., 2022, “Ozone-Based Processes in Dye Removal” in Advanced Oxidation Processes in Dye-Containing Wastewater: Volume 2, Eds. Muthu, S.S., and Khadir, A., Springer Nature Singapore, Singapore, 175–211.

[5] Pratiwi, R., Notodarmojo, S., and Helmy, Q., 2018, Decolourization of remazol black-5 textile dyes using moving bed bio-film reactor, IOP Conf. Ser.: Earth Environ. Sci., 106 (1), 012089.

[6] Suryawan, I.W.K., Helmy, Q., and Notodarmojo, S., 2020, Laboratory scale ozone-based post-treatment from textile wastewater treatment plant effluent for water reuse, J. Phys.: Conf. Ser., 1456 (1), 012002.

[7] Suryawan, I.W.K., Septiariva, I.Y., Helmy, Q., Notodarmojo, S., Wulandari, M., Sari, N.K., Sarwono, A., Pratiwi, R., and Lim, J.W., 2021, Comparison of ozone pre-treatment and post-treatment hybrid with moving bed biofilm reactor in removal of remazol black 5, Int. J. Technol., 12 (4), 727–738.

[8] Neolaka, Y.A.B., Lawa, Y., Naat, J.N., Riwu, A.A.P., Iqbal, M., Darmokoesoemo, H., and Kusuma, H.S., 2020, The adsorption of Cr(VI) from water samples using graphene oxide-magnetic (GO-Fe₃O₄) synthesized from natural cellulose-based graphite (Kusambi wood or Schleichera oleosa): Study of kinetics, isotherms and thermodynamics, J. Mater. Res. Technol., 9 (3), 6544–6556.

[9] Liu, S., Ma, C., Ma, M.G., and Xu, F., 2019, “Magnetic Nanocomposite Adsorbents” in Composite Nanoadsorbents, Eds. Kyzas, G.Z., and Mitropoulos, A.C., Elsevier, Amsterdam, Netherlands 295–316.

[10] Supriyanto, G., Rukman, N.K., Khoiron Nisa, A., Jannatin, M., Piere, B., Abdullah, A., Zakki Fahmi, M., and Septya Kusuma, H., 2018, Graphene oxide from Indonesian biomass: Synthesis and characterization, BioResources, 13 (3), 4832–4840.

[11] Wang, H., Yuan, X., Wu, Y., Chen, X., Leng, L., Wang, H., Li, H., and Zeng, G., 2015, Facile synthesis of polypyrrole decorated reduced graphene oxide–Fe₃O₄ magnetic composites and its application for the Cr(VI) removal, Chem. Eng. J., 262, 597–606.

[12] Bagheri, A.R., Ghaedi, M., Asfaram, A., Bazrafshan, A.A., and Jannesar, R., 2017, Comparative study on ultrasonic assisted adsorption of dyes from single system onto Fe₃O₄ magnetite nanoparticles loaded on activated carbon: Experimental design methodology, Ultrason. Sonochem., 34, 294–304.

[13] Bhomick, P.C., Supong, A., Karmaker, R., Baruah, M., Pongener, C., and Sinha, D., 2019, Activated carbon synthesized from biomass material using single-step KOH activation for adsorption of fluoride: Experimental and theoretical investigation, Korean J. Chem. Eng., 36 (4), 551–562.

[14] Alam, S., Khan, M.S., Bibi, W., Zekker, I., Burlakovs, J., Ghangrekar, M.M., Bhowmick, G.D., Kallistova, A., Pimenov, N., and Zahoor, M., 2021, Preparation of activated carbon from the wood of Paulownia tomentosa as an efficient adsorbent for the removal of acid red 4 and methylene blue present in wastewater, Water, 13 (11), 1453.

[15] Moges, A., Nkambule, T.T.I., and Fito, J., 2022, The application of GO-Fe₃O₄ nanocomposite for chromium adsorption from tannery industry wastewater, J. Environ. Manage., 305, 114369.

[16] Cheruiyot, G.K., Wanyonyi, W.C., Kiplimo, J.J., and Maina, E.N., 2019, Adsorption of toxic crystal violet dye using coffee husks: Equilibrium, kinetics and thermodynamics study, Sci. Afr., 5, e00116.

[17] Sammaiah, A., Huang, W., and Wang, X., 2018, Synthesis of magnetic Fe₃O₄/graphene oxide nanocomposites and their tribological properties under magnetic field, Mater. Res. Express, 5 (10), 105006.

[18] Esmaeili, A., and Entezari, M.H., 2014, Facile and fast synthesis of graphene oxide nanosheets via bath ultrasonic irradiation, J. Colloid Interface Sci., 432, 19–25.

[19] Zhang, S., Wang, H., Liu, J., and Bao, C., 2020, Measuring the specific surface area of monolayer graphene oxide in water, Mater. Lett., 261, 127098.

[20] Li, S., 2019, Combustion synthesis of porous MgO and its adsorption properties, Int. J. Ind. Chem., 10 (1), 89–96.

[21] Cotoruelo, L.M., Marqués, M.D., Díaz, F.J., Rodríguez-Mirasol, J., Rodríguez, J.J., and Cordero, T., 2012, Lignin-based activated carbons as adsorbents for crystal violet removal from aqueous solutions, Environ. Prog. Sustainable Energy, 31 (3), 386–396.

[22] Othman, N.H., Alias, N.H., Shahruddin, M.Z., Abu Bakar, N.F., Nik Him, N.R., and Lau, W.J., 2018, Adsorption kinetics of methylene blue dyes onto magnetic graphene oxide, J. Environ. Chem. Eng., 6 (2), 2803–2811.

[23] Mahmoud, M.A., 2020, Oil spill cleanup by raw flax fiber: Modification effect, sorption isotherm, kinetics and thermodynamics, Arabian J. Chem., 13 (6), 5553–5563.

[24] Chen, F., Liang, W., Qin, X., Jiang, L., Zhang, Y., Fang, S., and Luo, D., 2021, Preparation and recycled simultaneous adsorption of methylene blue and Cu²⁺ co-pollutants over carbon layer encapsulated Fe₃O₄/graphene oxide nanocomposites rich in amino and thiol groups, Colloids Surf., A, 625, 126913.

[25] Shoushtarian, F., Moghaddam, M.R.A., and Kowsari, E., 2020, Efficient regeneration/reuse of graphene oxide as a nanoadsorbent for removing basic Red 46 from aqueous solutions, J. Mol. Liq., 312, 113386.

[26] Ciğeroğlu, Z., Haşimoğlu, A., and Özdemir, O.K., 2021, Synthesis, characterization and an application of graphene oxide nanopowder: Methylene blue adsorption and comparison between experimental data and literature data, J. Dispersion Sci. Technol., 42 (5), 771–783.

[27] Bonilla-Petriciolet, A., Mendoza-Castillo, D.I., and Reynel-Ávila, H.E., 2017, Adsorption Processes for Water Treatment and Purification, Springer Cham, Switzerland.

[28] Ragadhita, R., and Nandiyanto, A.B.D., 2021, How to calculate adsorption isotherms of particles using two-parameter monolayer adsorption models and equations, Indones. J. Sci. Technol., 6 (1), 205–234.

[29] Mozaffari Majd, M., Kordzadeh-Kermani, V., Ghalandari, V., Askari, A., and Sillanpää, M., 2022, Adsorption isotherm models: A comprehensive and systematic review (2010−2020), Sci. Total Environ., 812, 151334.

[30] Alrobei, H., Prashanth, M.K., Manjunatha, C.R., Kumar, C.B.P., Chitrabanu, C.P., Shivaramu, P.D., Kumar, K.Y., and Raghu, M.S., 2021, Adsorption of anionic dye on eco-friendly synthesised reduced graphene oxide anchored with lanthanum aluminate: Isotherms, kinetics and statistical error analysis, Ceram. Int., 47 (7, Part B), 10322–10331.

[31] Oprea, A., Degler, D., Barsan, N., Hemeryck, A., and Rebholz, J., 2019, “Basics of Semiconducting Metal Oxide–based Gas Sensors” in Gas Sensors Based on Conducting Metal Oxides, Eds. Barsan, N., and Schierbaum, K., Elsevier, Amsterdam, Netherlands, 61–165.

[32] Rahman, D.A., Helmy, Q., Syafila, M., and Gumilar, A., 2022, Adsorption of dyes using graphene oxide-based nano-adsorbent: A review, Jurnal Presipitasi, 19 (2), 384–397.

[33] Faghihi, A., Vakili, M.H., Hosseinzadeh, G., Farhadian, M., and Jafari, Z., 2016, Synthesis and application of recyclable magnetic freeze-dried graphene oxide nanocomposite as a high capacity adsorbent for cationic dye adsorption, Desalin. Water Treat., 57 (47), 22655–22670.

DOI: https://doi.org/10.22146/ijc.80894