A Review on Expired Drug-Based Corrosion Inhibitors: Chemical Composition, Structural Effects, Inhibition Mechanism, Current Challenges, and Future Prospects

https://doi.org/10.22146/ijc.64048

Muhamad Jalil Baari(1*), Carla Wulandari Sabandar(2)

(1) Department of Chemistry, Faculty of Science and Technology, Universitas Sembilanbelas November Kolaka, Jl. Pemuda, Kolaka 93517, Indonesia
(2) Department of Pharmacy, Faculty of Science and Technology, Universitas Sembilanbelas November Kolaka, Jl. Pemuda, Kolaka 93517, Indonesia
(*) Corresponding Author

Abstract


This comprehensive review highlighted how the expired drugs manage corrosion reactions on metal/alloy surfaces, especially types of carbon/mild steel, Sabic iron, copper, and aluminium in NaCl or acid solution. Several types of expired drugs and the optimum conditions presented in this review were summarized from relevant studies. The performance of expired drugs which covers inhibition efficiency, inhibition mechanisms, and metal surface analysis was informed. The contribution of the chemical composition, molecular structure, compatible treatment conditions, and some corrosion analysis methods were mentioned. Current challenges and future prospects were also discussed for further investigations and developments to obtain superior inhibitors and save the environment.


Keywords


corrosion; corrosion inhibitor; expired drugs; carbon steel; copper; aluminium

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References

[1] Ye, Y., Yang, D., Chen, H., Guo, S., Yang, Q., Chen, L., Zhao, H., and Wang, L., 2020, A high-efficiency corrosion inhibitor of N-doped citric acid-based carbon dots for mild steel in hydrochloric acid environment, J. Hazard. Mater., 381, 121019.

[2] Burstein, G.T., Liu, C., Souto, R.M., and Vines, S.P., 2004, Origins of pitting corrosion, Corros. Eng. Sci. Technol., 39 (1), 25–30.

[3] Song, F.M., Kirk, D.W., Graydon, J.W., and Cormack, D.E., 2004, Predicting carbon dioxide corrosion of bare steel under an aqueous boundary layer, Corrosion, 60 (8), 736–748.

[4] Hagarová, M., Cervová, J., and Jaš, F., 2015, Selected types of corrosion degradation of pipelines, Koroze Ochr. Mater., 59 (1), 30–36.

[5] AER, 2013, Report 2013-B: Pipeline Performance in Alberta, 1990–2012, Alberta Energy Regulator, Calgary, Alberta, Canada.

[6] Koch, G., Varney, J., Thopson, N., Moghissi, O., Gould, M., and Payer, J., 2016, International Measures of Prevention, Application, and Economics of Corrosion Technologies Study, Eds. Jacobson, G., NACE International, Houston, Texas, USA.

[7] Jafar Mazumder, M.A., 2020, A review of green scale inhibitors: Process, types, mechanism and properties, Coatings, 10 (10), 928.

[8] Dickinson, W., Sanders, L., and Lowen, C., 2011, Development and Performance of Biodegradable Antiscalants for Oilfield Applications, Offshore Technology Conference 2011 (OTC 2011), Houston, Texas, USA, 2–5 May 2011.

[9] Popoola, L.T., Grema, A.S., Latinwo, G.K., Gutti, B., and Balogun, A.S., 2013, Corrosion problems during oil and gas production and its mitigation, Int. J. Ind. Chem., 4 (1), 35.

[10] Dahiya, S., Lata, S., Kumar, R., and Yadav, O.S., 2016, Comparative performance of Uroniums for controlling corrosion of steel with methodical mechanism of inhibition in acidic medium: Part1, J. Mol. Liq., 221, 124–132.

[11] Kumar, C.M., Chandrashekarappa, M.P., Kulkarni, R.M., Pimenov, D.Y., and Giasin, K., 2021, The effect of Zn and Zn–WO3 composites nano-coatings deposition on hardness and corrosion resistance in steel substrate, Materials, 14 (9), 2253.

[12] Duong, N.T., Hang, T.T.X., Nicolay, A., Paint, Y., and Olivier, M.G., 2016, Corrosion protection of carbon steel by solvent free epoxy coating containing hydrotalcites intercalated with different organic corrosion inhibitors, Prog. Org. Coat., 101, 331–341.

[13] Cotting, F., and Aoki, I.V., 2016, Smart protection provided by epoxy clear coating doped with polystyrene microcapsules containing silanol and Ce (III) ions as corrosion inhibitors, Surf. Coat. Technol., 303 (Part B), 310–318.

[14] Eugenio, F.D.T., and Pajarito, B.B., 2019, Potential anti-corrosion additives derived from waste plastic sachets, IOP Conf. Ser.: Mater. Sci. Eng., 634 (1), 012039.

[15] Singh, A., Ansari, K., Quraishi, M., and Banerjee, P., 2021, Corrosion inhibition and adsorption of imidazolium based ionic liquid over P110 steel surface in 15% HCl under static and dynamic conditions: Experimental, surface and theoretical analysis, J. Mol. Liq., 323, 114608.

[16] Baari, M.J., Bundjali, B., and Wahyuningrum, D., 2020, Synthesis of oligosuccinimide and evaluation of its corrosion inhibition performance on carbon steel in CO2-saturated 1% NaCl solution, J. Math. Fundam. Sci., 52 (2), 202–221.

[17] Baari, M.J., Bundjali, B., and Wahyuningrum, D., 2021, Performance of N,O-carboxymethyl chitosan as corrosion and scale inhibitors in CO2 saturated brine solution, Indones. J. Chem., Article in Press.

[18] Pahuja, P., Dahiya, S., and Lata, S., 2018, Review on herbal drugs as corrosion inhibitor for low alloy steel, BMIET J. Sci. Technol. Manage., 2 (1), 7–19.

[19] Agrawal, Y.K., Talati, J.D., Shah, M.D., Desai, M.N., and Shah, N.K., 2004, Schiff bases of ethylenediamine as corrosion inhibitors of zinc in sulphuric acid, Corros. Sci., 46 (3), 633–651.

[20] Ashassi-Sorkhabi, H., Shaabani, B., and Seifzadeh, D., 2005, Effect of some pyrimidinic Shciff bases on the corrosion of mild steel in hydrochloric acid solution, Electrochim. Acta, 50 (16-17), 3446–3452.

[21] Tamalmani, K., and Husin, H., 2020, Review on corrosion inhibitors for oil and gas corrosion issues, Appl. Sci., 10 (10), 3389.

[22] Geethamani, P., and Kasthuri, P.K., 2015, Adsorption and corrosion inhibition of mild steel in acidic media by expired pharmaceutical drug, Cogent Chem., 1 (1), 1091558.

[23] Srivastava, M., Tiwari, P., Srivastava, S.K., Prakash, R., and Ji, G., 2017, Electrochemical investigation of Irbesartan drug molecules as an inhibitor of mild steel corrosion in 1 M HCl and 0.5 M H2SO4 solutions, J. Mol. Liq., 236, 184–197.

[24] El-Haddad, M.N., Fouda, A.S., and Hassan, A.F., 2019, Data from chemical, electrochemical and quantum chemical studies for interaction between Cephapirin drug as an eco-friendly corrosion inhibitor and carbon steel surface in acidic medium, Chem. Data Collect., 22, 100251.

[25] Ayoola, A.A., Fayomi, O.S.I., and Ogunkanmbi, S.O., 2018, Data on inhibitive performance of Chloraphenicol drug on A315 mild steel in acidic medium, Data Brief, 19, 804–809.

[26] Abdallah, M., Gad, E.A.M., Sobhi, M., Al-Fahemi, J.H., and Alfakeer, M.M., 2019, Performance of tramadol drug as a safe inhibitor for aluminum corrosion in 1.0 M HCl solution and understanding mechanism of inhibition using DFT, Egypt. J. Pet., 28 (2), 173–181.

[27] Adejoro, I.A., Ojo, F.K., and Obafemi, S.K., 2015, Corrosion inhibition potentials of ampicillin for mild steel in hydrochloric acid solution, J. Taibah Univ. Sci., 9 (2), 196–202.

[28] Ansari, K., Quraishi, M., Prashant, and Ebenso, E., 2013, Electrochemical and thermodynamic investigation of diclofenac sodium drug as a potential corrosion inhibitor for mild steel in hydrochloric acid, Int. J. Electrochem. Sci., 8 (12), 12860–12873.

[29] Vaszilcsin, N., Ordodi, V., and Borza, A., 2012, Corrosion inhibitors from expired drugs, Int. J. Pharm., 431 (1-2), 241–244.

[30] Fouda, A.S., Mahmoud, W.M., and Abdul Mageed, H.A., 2016, Evaluation of an expired nontoxic amlodipine besylate drug as a corrosion inhibitor for low-carbon steel in hydrochloric acid solutions, J. Bio- Tribo-Corros., 2 (2), 7.

[31] Attia, E.M., 2015, Expired farcolin drug as corrosion inhibitor for carbon steel in 1 M HCl solution, J. Basic Appl. Chem., 5 (1), 1–15.

[32] Pathak, R.K., and Mishra, P., 2016, Drugs as corrosion inhibitors: A review, Int. J. Sci. Res., 5 (4), 671–677.

[33] Shamnamol, G.K., Sreelakshmi, K.P., Ajith, G., and Jacob, J.M., 2020, Effective utilization of drugs as green corrosion inhibitor-A review, AIP Conf. Proc., 2225, 70006.

[34] Gece, G., 2011, Drugs: A review of promising novel corrosion inhibitors, Corros. Sci., 53 (12), 3873–3898.

[35] Vaszilcsin, N., Duca, D.A., Flueraş, A., and Dan, M.L., 2019, Expired drugs as inhibitors in electrochemical processes – A mini-review, Stud. Univ. Babes-Bolyai Chem., 64 (3), 17–32.

[36] Srinivasulu, A., and Kasthuri, P.K., 2017, Study of inhibition and adsorption properties of mild steel corrosion by expired pharmaceutical Gentamicin drug in hydrochloric acid media, Orient. J. Chem., 33 (5), 2616–2624.

[37] Fouda, A.E.A., and El-Azaly, A.M., 2018, Expired concor drug as potential nontoxic corrosion inhibitor for 304 stainless steel in hydrochloric acid solution, Zast. Mater., 59 (2), 226–236.

[38] Abeng, F.E., Anadebe, V.C., Idim, V.D., and Edim, M.M., 2020, Anti-corrosion behaviour of expired Tobramycin drug on carbon steel in acidic medium, S. Afr. J. Chem., 73, 125–130.

[39] Chaudhari, L.P., and Patel, S.N., 2019, Corrosion inhibition study of expired acetazolamide on mild steel in dilute hydrochloric acid solution, J. Bio- Tribo-Corros., 5 (1), 20.

[40] Abdallah, M., Fawzy, A., and Al Bahir, A., 2020, The effect of expired acyclovir and omeprazole drugs on the inhibition of sabic iron corrosion in HCl solution, Int. J. Electrochem. Sci., 15, 4739–4753.

[41] Raghavendra, N., 2019, Expired amitriptyline drug as a new nontoxic inhibitor protecting mild steel corrosion in HCl solution, Sci. Lett., 7 (1), 26–31.

[42] Chaudhari, L.P., and Patel, S.N., 2018, Green approach to corrosion inhibition on mild steel in acidic media by the expired sulpha drug, Int. J. Manage. Technol. Eng., 8 (11), 665–678.

[43] Fouda, A.S., Ibrahim, H., Rashwaan, S., El-Hossiany, A., and Ahmed, R.M., 2018, Expired drug (pantoprazole sodium) as a corrosion inhibitor for high carbon steel in hydrochloric acid solution, Int. J. Electrochem. Sci., 13, 6327–6346.

[44] Dohare, P., Chauhan, D.S., Sorour, A.A., and Quraishi, M.A., 2017, DFT and experimental studies on the inhibition potentials of expired Tramadol drug on mild steel corrosion in hydrochloric acid, Mater. Discovery, 9, 30–41.

[45] Singh, P., Chauhan, D.S., Srivastava, K., Srivastava, V., and Quraishi, M.A., 2017, Expired atorvastatin drug as corrosion inhibitor for mild steel in hydrochloric acid solution, Int. J. Ind. Chem., 8 (4), 363–372.

[46] Dahiya, S., Saini, N., Dahiya, N., Lgaz, H., Salghi, R., Jodeh, S., and Lata, S., 2018, Corrosion inhibition activity of an expired antibacterial drug in acidic media amid elucidate DFT and MD simulations, Port. Electrochim. Acta, 36 (3), 213–230.

[47] Raghavendra, N., 2019, Effect of expired Oxazepam medicine on the corrosion of carbon steel in 5% NaCl solution: An experimental approach towards mitigation of dissolution process, Front. Chem. Res., 1 (1), 1–4.

[48] Raghavendra, N., 2019, Use of expired Naftifine drug as corrosion inhibitor for copper in hydrochloric acid, J. Adv. Electrochem., 5 (1), 177–179.

[49] Raghavendra, N., Hublikar, L.V., and Ganiger, P.J., 2019, Expired Ixabepilone as a corrosion inhibitor on copper metal protection in 5 M HCl medium, Int. J. Res. Chem. Sci., 6 (4), 1–3.

[50] Abdel Hameed, R.S., Ismail, E.A., Abu-Nawwas, A.H., and Al-Shafey, H.I., 2015, Expired voltaren drugs as corrosion inhibitor for aluminium in hydrochloric acid, Int. J. Electrochem. Sci., 10, 2098–2109.

[51] Raghavendra, N., 2019, Expired lorazepam drug: A medicinal compound as green corrosion inhibitor for mild steel in hydrochloric acid system, Chem. Afr., 2 (3), 463–470.

[52] Geethamani, P., and Kasthuri, P.K., 2016, The inhibitory action of expired asthalin drug on the corrosion of mild steel in acidic media: A comparative study, J. Taiwan Inst. Chem. Eng., 63, 490–499.

[53] Eid, S., 2021, Expired Desloratidine drug as inhibitor for corrosion of carbon steel pipeline in hydrochloric acid solution, Int. J. Electrochem. Sci., 16, 150852.

[54] Onyeachu, I.B., Abdel-Azeim, S., Chauhan, D.S., and Quraishi, M.A., 2021, Electrochemical and computational insights on the application of expired Metformin drug as a novel inhibitor for the sweet corrosion of C1018 steel, ACS Omega, 6 (1), 65–76.

[55] Abdel Hameed, R.S., Ismail, E.A., Al-Shafey, H.I., and Abbas, M.A., 2020, Expired Indomethacin therapeutics as corrosion inhibitors for carbon steel in 1.0 M hydrochloric acid media, J. Bio- Tribo-Corros., 6 (4), 114.

[56] Al-Shafey, H.I., Abdel Hameed, R.S., Ali, F.A., Aboul-Magd, A.E.A.S., and Salah, M., 2014, Effect of expired drugs as corrosion inhibitors for carbon steel in 1 M HCL solution, Int. J. Pharm. Sci. Rev. Res., 27 (1), 146–152.

[57] Abdel Hameed, R.S., 2011, Ranitidine drugs as non-toxic corrosion inhibitors for mild steel in hydrochloric acid medium, Port. Electrochim. Acta, 29 (4), 273–285.

[58] Dohare, P., Chauhan, D.S., and Quraishi, M.A., 2018, Expired podocip drug as potential corrosion inhibitor for carbon steel in acid chloride solution, Int. J. Corros. Scale Inhib., 7 (1), 25–37.

[59] Geethamani, P., Kasthuri, P., and and Aejitha, A., 2014, A new pharmaceutically expired drug acts as corrosion inhibitor for mild steel in acid medium, Elixir Corros. Dye, 76, 28406–28410.

[60] Nathiya, R.S., Perumal, S., Murugesan, V., and Raj, V., 2018, Expired drugs: Environmentally safe inhibitors for aluminium corrosion in 1 M H2SO4, J. Bio- Tribo-Corros., 4 (1), 4.

[61] Gupta, N.K., Gopal, C.S.A., Srivastava, V., and Quraishi, M.A., 2017, Application of expired drugs in corrosion inhibition of mild steel, Int. J. Pharm. Chem. Anal., 4 (1), 8–12.

[62] Rout, T.K., 2007, Electrochemical impedance spectroscopy study on multi-layered coated steel sheets, Corros. Sci., 49 (2), 794–817.

[63] Berdimurodov, E., Akbarov, K., and Kholikov, A., 2019, Electrochemical frequency modulation and reactivation investigation of thioglycolurils in strong acid medium, Adv. Mater. Res., 1154, 122–128.

[64] Nagalakshmi, R., Nagarajan, L., Rathish, R., Prabha, S., Vijaya, N., Jeyasundari, J., and Rajendran, S., 2014, Corrosion resistance of SS316l in artificial urine in presence ff D-glucose, Int. J. Nano Corros. Sci. Eng., 1, 39–49.

[65] Huang, H., Yao, Q., Jiao, Q., Liu, B., and Chen, H., 2019, Polyepoxysuccinic acid with hyper-branched structure as an environmentally friendly scale inhibitor and its scale inhibition mechanism, J. Saudi Chem. Soc., 23 (1), 61–74.

[66] Abdel Hameed, R.S., AlShafey, H.I., and Abu-Nawwas, A.H., 2014, 2-(2, 6-Dichloranilino) phenyl acetic acid drugs as eco-friendly corrosion inhibitors for mild steel in 1 M HCl, Int. J. Electrochem. Sci., 9, 6006–6019.

[67] Fouda, A.S., El Morsi, M.A., and El Mogy, T., 2017, Studies on the inhibition of carbon steel corrosion in hydrochloric acid solution by expired Carvedilol drug, Green Chem. Lett. Rev., 10 (4), 336–345.

[68] Raghavendra, N., 2018, The corrosion inhibition study of expired Doxercalciferol drug as nontoxic inhibitor for mild steel (MS) in 3 M HCl medium, J. Chem. Pharm. Res., 10 (12), 1–6.

[69] Raghavendra, N., 2018, Expired Fluoxymesterone drug as sustainable corrosion inhibitor for mild steel (MS) in 3 M HCl solution: Experimental investigations towards mitigation of metal dissolution, Int. J. Chem. Mater. Res., 6 (1), 1–7.

[70] Fadila, B., Sihem, A., Sameh, A., and Kardas, G., 2019, A study on the inhibition effect of expired amoxicillin on mild steel corrosion in 1 N HCl, Mater. Res. Express, 6 (4), 46419.

[71] Singh, A.K., Chugh, B., Saha, S.K., Banerjee, P., Ebenso, E.E., Thakur, S., and Pani, B., 2019, Evaluation of anti-corrosion performance of an expired semi synthetic antibiotic cefdinir for mild steel in 1 M HCl medium: An experimental and theoretical study, Results Phys., 14, 102383.

[72] Anaee, R.A., Tomi, I.H.R., Abdulmajeed, M.H., Naser, S.A., and Kathem, M.M., 2019, Expired Etoricoxib as a corrosion inhibitor for steel in acidic solution, J. Mol. Liq., 279, 594–602.

[73] Abdallah, M., Fawzy, A., and Al Bahir, A., 2020, Expired amoxicillin and cefuroxime drugs as efficient anticorrosives for Sabic iron in 1.0 M hydrochloric acid solution, Chem. Eng. Commun., 0 (0), 1–28.

[74] Anaee, R.A., Abd Al-Majeed, M.H., Naser, S.A., Kathem, M.M., and Ahmed, O.A., 2019, Antibacterial inhibitor as an expired metoclopramide in 0.5 M phosphoric acid, Al-Khwarizmi Eng. J., 15 (1), 71–81.

[75] Raghavendra, N., Hublikar, L.V., Patil, S.M., Ganiger, P.J., Bhinge, A.S., and Chitnis, S., 2019, Corrosion protection of expired Perindopril and expired Alprazolam drug in carbon steel in the 3% NaCl solution, Int. J. Pharm. Biol. Sci., 9 (3), 838–842.

[76] Quraishi, M.A., and Rawat, J., 2000, Corrosion inhibition of mild steel in acid solutions by tetramethyl‐dithia‐octaazacyclotetradeca hexaene (MTAT), Anti-Corros. Methods Mater., 47 (5), 288–293.

[77] Jamil, H.E., Shriri, A., Boulif, R., Montemor, M., and Ferreira, M., 2005, Corrosion behaviour of reinforcing steel exposed to an amino alcohol based corrosion inhibitor, Cem. Concr. Compos., 27 (6), 671–678.

[78] Yoo, S.H., Kim, Y.W., Chung, K., Baik, S.Y., and Kim, J.S., 2012, Synthesis and corrosion inhibition behavior of imidazoline derivatives based on vegetable oil, Corros. Sci., 59, 42–54.

[79] Kasshanna, S., and Rostron, P., 2017, Novel synthesis and characterization of vegetable oil derived corrosion inhibitors, J. Mater. Environ. Sci., 8 (12), 4292–4300.

[80] Weng, C.J., Peng, C.W., Chang, C.H., Chang, Y.H., and Yeh, J.M., 2012, Corrosion resistance conferred by superhydrophobic fluorinated polyacrylate–silica composite coatings on cold-rolled steel, J. Appl. Polym. Sci., 126 (S2), E48–E55.

[81] Liu, F.G., Du, M., Zhang, J., and Qiu, M., 2009, Electrochemical behavior of Q235 steel in saltwater saturated with carbon dioxide based on new imidazoline derivative inhibitor, Corros. Sci., 51 (1), 102–109.

[82] Tang, Z., 2019, A review of corrosion inhibitors for rust preventative fluids, Curr. Opin. Solid State Mater. Sci., 23 (4), 100759.

[83] Gupta, R.K., Malviya, M., Ansari, K.R., Lgaz, H., Chauhan, D.S., and Quraishi, M.A., 2019, Functionalized graphene oxide as a new generation corrosion inhibitor for industrial pickling process: DFT and experimental approach, Mater. Chem. Phys., 236, 121727.

[84] Barmatov, E., Hughes, T., and Nagl, M., 2015, Efficiency of film-forming corrosion inhibitors in strong hydrochloric acid under laminar and turbulent flow conditions, Corros. Sci., 92, 85–94.

[85] Kahyarian, A., and Nesic, S., 2019, A new narrative for CO2 corrosion of mild steel, J. Electrochem. Soc., 166 (11), C3048–C3063.

[86] Lee, H.S., Saraswathy, V., Kwon, S.J., and Karthick, S., 2018, "Corrosion Inhibitors for Reinforced Concrete: A Review" in Corrosion Inhibitors, Principles and Recent Applications, Eds. Aliofkhazraei, M., IntechOpen, London, UK.

[87] Shukla, S.K., and Quraishi, M.A., 2009, Cefotaxime sodium: A new and efficient corrosion inhibitor for mild steel in hydrochloric acid solution, Corros. Sci., 51 (5), 1007–1011.

[88] Singh, A.K., and Quraishi, M.A., 2010, Effect of Cefazolin on the corrosion of mild steel in HCl solution, Corros. Sci., 52 (1), 152–160.

[89] Subekti, N., Soedarsono, J.W., Riastuti, R., and Sianipar, F.D., 2020, Development of environmental friendly corrosion inhibitor from the extract of areca flower for mild steel in acidic media, East.-Eur. J. Enterp. Technol., 2 (6 (104)), 34–45.

[90] Loto, R.T., Loto, C.A., Joseph, O., and Olanrewaju, G., 2016, Adsorption and corrosion inhibition properties of thiocarbanilide on the electrochemical behavior of high carbon steel in dilute acid solutions, Results Phys., 6, 305–314.

[91] Saadi, R., Saadi, Z., Fazaeli, R., and Fard, N.E., 2015, Monolayer and multilayer adsorption isotherm models for sorption from aqueous media, Korean J. Chem. Eng., 32 (5), 787–799.

[92] Langmuir, I., 1916, The Constitution and fundamental properties of solids and liquids. Part I. Solids, J. Am. Chem. Soc., 38 (11), 2221–2295.



DOI: https://doi.org/10.22146/ijc.64048

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