TRANSPORT OF PHENOL THROUGH INCLUSION POLYMER MEMBRANE (PIM) USING COPOLY(EUGENOL-DVB) AS MEMBRANE CARRIERS

https://doi.org/10.22146/ijc.21348

Agung Abadi Kiswandono(1*), Dwi Siswanta(2), Nurul Hidayat Aprilita(3), Sri Juari Santosa(4)

(1) Faculty of Public Health, Prima University, Medan
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281
(4) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281
(*) Corresponding Author

Abstract


Copoly(eugenol-DVB) with DVB composition of 2%, 6% and 12% had been prepared and characterized by FTIR spectroscopy. The copolymers were used as membrane carriers for the transport of phenol using the polymer inclusion membranes (PIM) based on polyvinylchloride (PVC) as membrane support. The experimental conditions for investigation of the transport of phenol through the membranes were pH of the source phase, NaOH concentration in the stripping phase, membrane thickness, phenol concentration and transport time. The results showed that the optimum condition for phenol transport was achieved on the membrane based on copoly(eugenol-DVB) 12% with the transport efficiency of 75.6% at pH of the source phase of 4.5, NaOH concentration of 0.25 M and transport time of 48 h. The reaction follows first order kinetics with mass transfer coefficient (k) of 1.02×10-5 m/s and permeability (Ps) of 8.5×10-6 m/s.

Keywords


crosslinked polymer; polymer inclusion membranes; membrane carrier; divinylbenzene

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References

[1] Gonzalez-Muñoz, M.J., Luque, S., Alvarez, J.R., and Coca, J., 2003, J. Membr. Sci., 213, 1-2, 181–193.

[2] De Gyves, J., and de san Miguel, E.R., 1999, Ind. Eng. Chem. Res., 38, 6, 2182–2202.

[3] Stanisavljvici, M., and Nidic, L., 2004, Working Living Environ. Prot., 2, 4, 345–349.

[4] Yang, X.J., Fane A.G., and Fell, C.J.D, 2003, Ind. Eng. Chem. Res., 42, 2, 392–403.

[5] Nghiem, L.D., Mornane, P., Potter, I.D., Perera, J.M., Cattrall, R.W., and Kolev, S.D., 2006, J. Membr. Sci., 281, 7–41.

[6] Kocherginsky, N.M., Yang, Q., and Seelam, L., 2007, Sep. Purif. Technol., 53, 171–177.

[7] Venkateswaran P., and Palanivelu K., 2006, J. Hazard. Mater., 131, 146–152.

[8] Huidong, Z., Biyu, W., Yanxiang, W.U., and Qilong, R.E.N., 2009, Chin. J. Chem. Eng., 17, 5, 750–755.

[9] Hill, C., Dojol, J.F., Rouquette, H., Eymard, S., and Tournois, B., 1996, J. Membr. Sci., 114, 1, 73–80.

[10] Gardner, J.S., Peterson, Q.P., Walker, J.O., Jensen, B.D., Adhikary, B., Harrison, R.G., and Lamb, J.D., 2006, J. Membr. Sci., 277, 165-167.

[11] Fontas, C., Tayeb, R., Dhahbi, M., Gaudichet, E., Thominette, F., Roy, P., Steenkeste, K., Fontaine-Aupart, M., Tingry, S., Tronel-Peyroz, E., and Seta, P., 2007, J. Membr. Sci., 290, 1-2, 62–72.

[12] Lamb, J.D., West, J.N., Shaha, D.P., and Johnson, J.C., 2010, J. Membr. Sci., 365, 256–259.

[13] Kim, J.S., Lee, S.H., Yu, S.H., Cho, M.H., Kim, D.W., Kwon S.G., and Lee, E.H., 2002, Bull. Korean Chem. Soc., 23, 8, 1085–1088.

[14] Tayeb, R., Fontas, C., Dhahbi, M., Tingry, S., and Seta, P., 2005, Sep. Purif. Technol., 42, 2, 189–193.

[15] Levitskaia, T.G., Lamb, J.D., Fox, K.L., and Moyer, B.A., 2002, Radiochim. Acta, 90, 1, 43–52.

[16] Kim, J.S., Kim, S.K., Cho, M.H., Lee, S.H., Kim, J.Y., Kwon, S.G., and Lee, E.H., 2001, Bull. Korean Chem. Soc., 22, 10, 1076–1080.

[17] Scindia, Y.M., Pandey, A.K., and Reddy, A.V.R., 2005, J. Membr. Sci., 249, 1-2, 143–152.

[18] Li, J.M., Meng, X.G., Hu, C.W., and Du, J., 2009, Bioresour. Technol., 100, 3, 1168–1173.

[19] Sousa, A.R., and Trancoso, M.A., 2009, Talanta, 79, 3, 796–803.

[20] Correia, P.F.M.M., and de Carvalho, J.M.R., 2003, J. Hazard. Mater., 225, 1-2, 41–49.

[21] Mortaheb, H.R., Amini, M.H., Sadeghian, F., Mokhtarani, B., and Daneshyar, H., 2008, J. Hazard. Mater., 160, 2-3, 582–588.



DOI: https://doi.org/10.22146/ijc.21348

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