Synthesis and Characterization of [Fe(picolinate)3][MnNi(oxalate)3].CH3OH Polymeric Complex

https://doi.org/10.22146/ijc.21244

Fahimah Martak(1*), Djulia Onggo(2), Ismunandar Ismunandar(3), Agung Nugroho(4)

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Surabaya 60111
(2) Inorganic and Physical Chemistry Research Division, Faculty of Mathematics and Natural Sciences, Bandung Institute of Technology, Jl. Ganesa 10 Bandung 40132
(3) Inorganic and Physical Chemistry Research Division, Faculty of Mathematics and Natural Sciences, Bandung Institute of Technology, Jl. Ganesa 10 Bandung 40132
(4) Physics of Magnetism an Photonics Research Division, Faculty of Mathematics and Natural Sciences, Bandung Institute of Technology, Jl. Ganesa 10 Bandung 40132
(*) Corresponding Author

Abstract


Polymeric complex [Fe(picolinate)3][MnNi(oxalate)3].CH3OH has been successfully synthesized using H-tube technique. The chemical composition of the synthesized product was determined by Elemental Analysis and Atomic Absorption Spectrometry. Infrared spectrum shows that the oxalate ligand acts as a bridging ligand. The crystalline product exists in the form of monoclinic structure and space group P21n as shown on the pattern of X-Ray Diffraction and has a similar structure with [Fe(bpp)2][MnCr(oxalate)3] complex. The magnetic susceptibility of the polymeric complex exhibits high spin and paramagnetic behavior.

Keywords


polymeric complex; bridging oxalate; picolinate ligand; paramagnetic behavior

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DOI: https://doi.org/10.22146/ijc.21244

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