Retrogradation Properties of Heat Moisture Treated (HMT) Sago and Arenga Starches

https://doi.org/10.22146/ifnp.44080

Dede Robiatul Adawiyah(1*), Tomoko Sasaki(2), Kaoru Kohyama(3)

(1) Bogor Agricultural University
(2) National Agriculture and Food Research Organization, NARO
(3) National Agriculture and Food Research Organization, NARO
(*) Corresponding Author

Abstract


This study aimed to investigate the retrogradation rate of heat moisture treated sago and arenga starches using different approaches, including a thermal approach using DSC (differential scanning calorimetry), a rheological approach using dynamic viscoelasticity as rheological and syneresis level. The autoclaving procedures prepared the HMT starches at 20% moisture content and warmed to 120 °C for 60 min and 90 min for sago and arenga starches, respectively. The Avrami equation was used to express starch retrogradation kinetics based on gelatinization enthalpy (ΔH). The Avrami exponent (n) of HMT and native starches were close to 1.0 (0.77 – 1.20) indicates rapid nuclei growth of the crystal. HMT has a significant influence on the retrogradation of sago starch, both from the values of n and k of the Avrami equation. On the other hand, it does not have a significant effect on arenga starch. Based on the thermal approach (DSC), HMT significantly affects sago starch’s retrogradation rate, but there was no effect on arenga starch. The influence of HMT on the retrogradation rate of arenga starch was observed on rheology and syneresis approaches, although it was not as high as sago starch.


Keywords


enthalpy; syneresis; avrami equation; rheology

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References

Adawiyah, D. R., Sasaki, T., and Kohyama, K. 2013.Characterization of arenga starch in comparison with sago starch. Carbohydrate Polimers 92: 2306-2313.

Adawiyah, D. R., Akuzawa, S., Sasaki, T., and Kohyama, K. 2017. A comparison of the effect of heat moisture treatment (HMT) on rheological properties and amylopectin structure in sago (Metroxylon sago) and arenga (Arenga pinnata) starches. Journal of Food Science and Technology. 54(11):3404-3410.

Adebowale, K. O., Henle, T., Schwarzenbolz, U., and Doert, T. 2009. Modification and properties of African yam bean (Sphenostylis stenocarpa Hochst. Ex A. Rich) Harms starch I: heat moisture treatment and annealing. Food Hydrocolloids 23: 1947-1957.

Cahyana Y., Wijaya E., Halimaha T.S., Martab H., Suryadic E., Kurniatia D. 2019. The effect of different thermal modifications on slowly digestible starch and physicochemical properties of green banana flour (Musa acuminata colla). Food Chemistry 274: 274-280.

Charoenrein S., Tatirat O., and Muadklay J. 2008. Use of CentrifugationFiltration for Determination of Syneresis in Freeze-thaw Starch Gels. Carbohydrate Polymer 73: 143-147

Jouppila, K., Kansikas, J., Ross, Y.H. 1998. Factors affecting crystallization and crystallization kinetics in amorphous corn starch. Carbohydrate Polymers, 36: 143-149

Karim, A. A., Norziah, M. H., and Seow, C. C. 2000. Review: methods for the study of starch retrogradation. Food Chemistry 71: 9-36.

Li, W., Li, C., Gu, Z., Qiu, Y., Cheng, L., Hong, Y., Li, Z. 2016. Retrogradation behavior of corn starch treated with 1,4-a-glucan branching enzyme. Food Chemistry 203:308–313.

Li, Y., Liu, S., Liu, X., Tang, X., Zhang, J. 2017. The impact of heatmoisture treatment on physicochemical properties and retrogradation behavior of sweet potato starch. International Journal of Food Engineering. 20170001

McIver, R. G., Axford, D. W. E., Colwell, K. H., and Elton, G. A. 1968. Kinetic study of the retrogradation of gelatinized starch. Journal of Science, Food and Agriculture 19: 560-563.

Takaya, T., Sano, C., and Nishinari, K. 2000. Thermal studies on the gelatinization and retrogradation of heat-moisture treated starch. Carbohydrate Polymers 41: 97-100.

Wang M., Muqi Sun M., Zhang Y., Chen Y., Wu Y., Ouyang J. 2019. Effect of microwave irradiation-retrogradation treatment on the digestive and physicochemical properties of starches with different crystallinity. Food Chemistry 298: 125015

Zavareze, E. R., and Dias, A. R. G. 2011. Impact of heat moisture treatment and annealing in starches: A review. Carbohydrate polymers 83: 317328.



DOI: https://doi.org/10.22146/ifnp.44080

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Indonesian Food and Nutrition Progress (print ISSN 0854-6177, online ISSN 2597-9388) is published by the Indonesian Association of Food Technologist in collaboration with Department of Food and Agricultural Product Technology, Faculty of Agricultural Technology, Universitas Gadjah Mada.

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