Enhancing the Anti-Fouling Property of Polyethersulfone-based Membrane using Chitosan Additive from Golden Snail (Pomacea canaliculata) Shell Waste for Water Purification

https://doi.org/10.22146/ajche.79643

Sri Mulyati(1*), Cut Meurah Rosnelly(2), Yanna Syamsuddin(3), Nasrul Arahman(4), Syawaliah Muchtar(5), Wahyuni Wahyuni(6), Tiara Lauzia(7), Aulia Chintia Ambarita(8), Muhammad Roil Bilad(9), Shafirah Samsuri(10)

(1) Department of Chemical Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
(2) Department of Chemical Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
(3) Department of Chemical Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
(4) Department of Chemical Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
(5) Department of Chemical Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
(6) Department of Chemical Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
(7) Department of Chemical Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
(8) Doctoral Program, School of Engineering Science, Syiah Kuala University, Banda Aceh 23111, Indonesia
(9) Faculty of Integrated Technologies, Universiti Brunei Darussalam, Jalan Tungku Link, Gadong, BE 1410, Brunei
(10) Chemical Engineering Department, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Perak, Malaysia
(*) Corresponding Author

Abstract


One of the common techniques for treating water and water from waste effluent is membrane filtration. Polymer is the main material that is most extensively employed as a substance for membranes. Because of its outstanding strength and resistance to chemicals, Polyethersulfone, also known as PES, is a common polymer used in the production of membranes. Unfortunately, its hydrophobicity makes it easy to foul when applied to water treatment processes. This study introduced a chitosan additive isolated from golden snail shell waste as an additive for PES-based membrane fabrication via blending at 0 wt%, 1 wt%, 3 wt%, 5 wt%, and 7 wt%. After preparation, the resultant membranes were analyzed and tested for their ability to filter a humic acid solution at a concentration of 50 mg L-1. According to the findings, the chitosan additive has the potential to change the characteristics of the membrane as well as its filtration performance. It increased the pure water flux from 110 181 L m-2 h-1 (no chitosan loading) to 181 L m-2 h-1 (for five wt% loadings). The membrane characterization results supported this increase in pure water flux, which showed that adding chitosan additives improved the porosity, size of pores, and hydrophilicity. The addition of this additive also has a good effect on the anti-fouling property by increasing the fouling recovery ratio (FRR). The FRRs for the modified membranes were 79% to 82%, which were higher than the neat PES membrane with an FRR of merely 60%.

Keywords


Chitosan; Humic Acid; Membrane Fouling; Pomacea canaliculata; Water Filtration

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References

Ali, I., 2012. “New generation adsorbents for water treatment.” Chemical Reviews 112, 5073–5091.

Al-Mubaddel, F.S., AlRomaih, H.S., Karim, M.R., Luqman, M., Al-Rashed, M.M., and Al-Mutairi, A.S., 2020. “Improved salt rejection, hydrophilicity and mechanical properties of novel thermoplastic polymer/chitosan nanofibre membranes.” Journal of Engineered Fibers and Fabrics,15.

Ayodele, O., Okoronkwo, A.E., Oluwasina, O.O., and Abe, T.O., 2018. “Utilization of blue crab shells for the synthesis of chitosan nanoparticles and their characterization.” Songklanakarin Journal of Science and Technology, 40, 1039–1042.

Chrzanowska, E., Gierszewska, M., Kujawa, J., Raszkowska-Kaczor, A., and Kujawski, W., 2018. “Development and characterization of polyamide- supported chitosan nanocomposite membranes for hydrophilic pervaporation.” Polymers, 10, 1–21.

Elizalde, C.N.B., Al-Gharabli, S., Kujawa, J., Mavukkandy, M., Hasan, S.W., and Arafat, H.A., 2018. “Fabrication of blend polyvinylidene fluoride/chitosan membranes for enhanced flux and fouling resistance.” Separation and Purification Technology, 190, 68–76.

Fathanah, U., Machdar, I., Riza, M., Arahman, N., Wahab, M.Y., Muchtar, S., Rosnelly, C.M., Mulyati, S., Syamsuddin, Y., Juned, S., and Razi, F., 2022. “Effect of hybrid Mg(OH)2/chitosan on the hydrophilicity and antifouling of polyethersulfone (PES) membrane.” Rasayan Journal of Chemistry, 15, 813–823.

Fathanah, U., Machdar, I., Riza, M., Arahman, N., Yusuf, M., Muchtar, S., Bilad, M.R., and Nordin, N.A.H., 2020. “Enhancement of antifouling of ultrafiltration polyethersulfone membrane with hybrid Mg (OH)2/chitosan by polymer blending.” Journal of Membrane Science and Research, 6, 375–382.

Foong, Y.X., Yew, L.H., and Chai, P. V., 2020. “Green approaches to polysulfone based membrane preparation via dimethyl sulfoxide and eco-friendly natural additive gum Arabic.” Materials Today: Proceedings, 46, 2092–2097.

Gao, K., Li, T., Liu, J., Dong, B., and Chu, H., 2019. “Ultrafiltration membrane fouling performance by mixtures with micromolecular and macromolecular organics.” Environmental Science: Water Research and Technology, 5, 277–286.

Geng, Z., Yang, Xue, Boo, C., Zhu, S., Lu, Y., Fan, W., Huo, M., Elimelech, M., and Yang, Xia, 2017. “Self-cleaning anti-fouling hybrid ultrafiltration membranes via side chain grafting of poly(aryl ether sulfone) and titanium dioxide.” Journal of Membrane Science, 529, 1–10.

Ghaemi, N., Daraei, P., and Akhlaghi, F.S., 2018. “Polyethersulfone nanofiltration membrane embedded by chitosan nanoparticles: Fabrication, characterization and performance in nitrate removal from water.” Carbohydrate Polymers ,191, 142–151.

Guan, Y.F., Qian, C., Chen, W., Huang, B.C., Wang, Y.J., and Yu, H.Q., 2018. “Interaction between humic acid and protein in membrane fouling process: A spectroscopic insight.” Water Research ,145, 146–152.

Hariani, P.L., Riyanti, F., Fatma, Rachmat, A., and Herbanu, A., 2020. “Removal of Pb(II) using hydroxyapatite from golden snail shell (Pomacea canaliculata l.) modified with silica.” Molekul, 15, 130–139.

Idris, A., Mat Zain, N., and Noordin, M.Y., 2007. “Synthesis, characterization and performance of asymmetric polyethersulfone (PES) ultrafiltration membranes with polyethylene glycol of different molecular weights as additives.” Desalination 207, 324–339.

Jubaedah, D., Wijayanti, M., Marsi, M., and Rizaldy, N., 2018. “Utilization of Golden Apple Snail (Pomacea canaliculata) S hells as Liming Materials for Pangasius sp Culture in Swamp Fish Pond.” E3S Web of Conferences, 68, 2–7.

Kouhestani, F., Torangi, M.A., Motavalizadehkakhky, A., Karazhyan, R., and Zhiani, R., 2019. “Enhancement strategy of polyethersulfone (PES) membrane by introducing pluronic F127/graphene oxide and phytic acid/graphene oxide blended additives: Preparation, characterization and wastewater filtration assessment.” Desalination and Water Treatment, 171, 44–56.

Kumar, R., Isloor, A.M., Ismail, A.F., and Matsuura, T., 2013. “Synthesis and characterization of novel water soluble derivative of chitosan as an additive for polysulfone ultrafiltration membrane.” Journal of Membrane Science, 440, 140–147.

Liu, J., Tian, C., Xiong, J., and Wang, L., 2017. “Polypyrrole blending modification for PVDF conductive membrane preparing and fouling mitigation.” Journal of Colloid and Interface Science, 494, 124–129.

Liu, R., Liu, S., Yu, J., Zhang, W., Dai, J., Zhang, Y., and Zhang, G., 2020. “The construction of a hydrophilic inorganic layer enables mechanochemically robust super antifouling UHMWPE composite membrane surfaces.” Polymers, 12, 1–17.

Miller, D.J., Paul, D.R., and Freeman, B.D., 2014. “An improved method for surface modification of porous water purification membranes.” Polymer, 55, 1375–1383.

Muchtar, S., Wahab, M.Y., Mulyati, S., Arahman, N., and Riza, M., 2019a. “Superior fouling resistant PVDF membrane with enhanced filtration performance fabricated by combined blending and the self-polymerization approach of dopamine.” Journal of Water Process Engineering, 28, 293–299.

Nasrollahi, N., Vatanpour, V., Aber, S., and Mohammad, N., 2018. “Preparation and characterization of a novel polyethersulfone (PES) ultra filtration membrane modified with a CuO / ZnO nanocomposite to improve permeability and antifouling properties.” Separation and Purification Technology, 192, 369–382.

Nayab, S.S., Abbas, M.A., Mushtaq, S., Niazi, B.K., Batool, M., Shehnaz, G., Ahmad, N., and Ahmad, N.M., 2021. “Anti-foulant ultrafiltration polymer composite membranes incorporated with composite activated carbon/chitosan and activated carbon/thiolated chitosan with enhanced hydrophilicity.” Membranes, 11, 827.

Ouda, M., Hai, A., Krishnamoorthy, R., Govindan, B., Othman, I., Kui, C.C., Choi, M.Y., Hasan, S.W., and Banat, F., 2022. “Surface tuned polyethersulfone membrane using an iron oxide functionalized halloysite nanocomposite for enhanced humic acid removal.” Environmental Research, 204, 112113.

Phewphong, S., Roschat, W., Pholsupho, P., Moonsin, P., Promarak, V., and Yoosuk, B., 2022. “Biodiesel production process catalyzed by acid-treated golden apple snail shells (Pomacea canaliculata)-derived CaO as a high-performance and green catalyst.” Engineering and Applied Science Research, 49, 36–46.

Rahmi, Julinawati, Nina, M., Fathana, H., and Iqhrammullah, M., 2022. “Preparation and characterization of new magnetic chitosan-glycine-PEGDE (Fe3O4/Ch-G-P) beads for aqueous Cd(II) removal.” Journal of Water Process Engineering, 45, 102493.

Rambabu, K., Bharath, G., Monash, P., Velu, S., Banat, F., Naushad, M., Arthanareeswaran, G., and Loke Show, P., 2019. “Effective treatment of dye polluted wastewater using nanoporous CaCl2 modified polyethersulfone membrane.” Process Safety and Environmental Protection, 124, 266–278.

Rekik, S.B., Gassara, S., Bouaziz, J., Deratani, A., and Baklouti, S., 2019. “Enhancing hydrophilicity and permeation flux of chitosan/kaolin composite membranes by using polyethylene glycol as porogen.” Applied Clay Science, 168, 312–323.

Shen, J. nan, Ruan, H. min, Wu, L. Guang, and Gao, C. Jie, 2011. “Preparation and characterization of PES-SiO2 organic-inorganic composite ultrafiltration membrane for raw water pretreatment.” Chemical Engineering Journal, 168, 1272–1278.

Sri Abirami Saraswathi, M., Kausalya, R., Kaleekkal, N.J., Rana, D., and Nagendran, A., 2017. “BSA and humic acid separation from aqueous stream using polydopamine coated PVDF ultrafiltration membranes.” Journal of Environmental Chemical Engineering, 5, 2937–2943.

Susanto, H., Robbani, M.H., Istirokhatun, T., Firmansyah, A.A., and Rhamadhan, R.N., 2020. “Preparation of low-fouling polyethersulfone ultrafiltration membranes by incorporating high-molecular-weight chitosan with the help of a surfactant.” South African Journal of Chemical Engineering, 33, 133–140.

Varma, R., and Vasudevan, S., 2020. “Extraction, characterization, and antimicrobial activity of chitosan from horse mussel modiolus modiolus.” ACS Omega, 5, 20224–20230.

Vatsha, B., Ngila, J.C., and Moutloali, R.M., 2014. “Preparation of antifouling polyvinylpyrrolidone (PVP 40K) modified polyethersulfone (PES) ultrafiltration (UF) membrane for water purification.” Physics and Chemistry of the Earth, 67–69, 125–131.

Wang, T. xu, Chen, S. ruo, Wang, T., Wu, L. guang, and Wang, Y. Xing, 2022. “PES mixed-matrix ultrafiltration membranes incorporating ZIF-8 and poly(ionic liquid) by microemulsion synthetic with flux and antifouling properties.” Applied Surface Science, 576, 151815.

Yuan, S., Li, Jian, Zhu, J., Volodine, A., Li, Jiansheng, Zhang, G., Van Puyvelde, P., and Van der Bruggen, B., 2018. “Hydrophilic nanofiltration membranes with reduced humic acid fouling fabricated from copolymers designed by introducing carboxyl groups in the pendant benzene ring.” Journal of Membrane Science, 563, 655–663.

Zhao, S., Tao, Z., Chen, L., Han, M., Zhao, B., Tian, X., Wang, L., and Meng, F., 2021. “An antifouling catechol/chitosan-modified polyvinylidene fluoride membrane for sustainable oil-in-water emulsions separation.” Frontiers of Environmental Science and Engineering, 15, 63.

Zhu, R., Diaz, A.J., Shen, Y., Qi, F., Chang, X., Durkin, D.P., Sun, Y., Solares, S.D., and Shuai, D., 2018. “Mechanism of humic acid fouling in a photocatalytic membrane system.” Journal of Membrane Science, 563, 531–540.



DOI: https://doi.org/10.22146/ajche.79643

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ASEAN Journal of Chemical Engineering  (print ISSN 1655-4418; online ISSN 2655-5409) is published by Chemical Engineering Department, Faculty of Engineering, Universitas Gadjah Mada.