Composite of Kaolin/Sodium Alginate (SA) Beads for Methylene Blue Adsorption

https://doi.org/10.22146/ajche.51457

Irwin Tan Kai Ge(1), Muhammad Wahyu Nugraha(2), Norashikin Ahmad Kamal(3), Nonni Soraya Sambudi(4*)

(1) Chemical Engineering Department, Universiti Teknologi PETRONAS 32610, Seri Iskandar, Malaysia
(2) Chemical Engineering Department, Universiti Teknologi PETRONAS 32610, Seri Iskandar, Malaysia
(3) Faculty of Civil Engineering, Universiti Teknologi Mara Shah Alam 40450, Selangor, Malaysia
(4) Chemical Engineering Department, Universiti Teknologi PETRONAS 32610, Seri Iskandar, Malaysia
(*) Corresponding Author

Abstract


Dyeing industry is one of the fast-growing industries but at the same time has also brought us a big issue on environment pollution. Adsorption processes is the most effective method in dye removal compared to other methods of wastewater treatment. In recent years, there is an increasing interest in utilizing clay material such as kaolinite as an adsorbent to remove not only inorganic but also organic molecules. In this study, composite of kaolin-sodium alginate (SA) beads was synthesized by varying the weight of kaolin from 0.5 g to 2 g. XRD, FTIR, and surface area analyses were used to characterize the kaolin; while FTIR was used to characterize the composite where the functional groups of kaolin and SA are existing. The amount of 1 g kaolin in SA could improve the adsorption of methylene blue up to 78% of removal after 8 hours. The adsorption model fits pseudo second order kinetic and Langmuir isotherm


Keywords


Kaolin; Composite; Sodium alginate; Adsorption; Pollutant removal

Full Text:

PDF


References

Abd El-Latif, M., Latif, E., Elkady M., Ibrahim, A. and Ossman, M. (2010). "Alginate/ Polyvinyl Alcohol -Kaolin Composite for Removal of Methylene Blue from Aqueous Solution in a Batch Stirred Tank Reactor." J. Am. Sci., 6, 280-292.

2. Alam, S., Amin, N.-u., Bangash, F. K. and Ali, M. (2014). "Removal of Basic Red 5 on Calcined Kaolinite – Characterization and Adsorption Kinetics." Tenside Surfact. Det., 51(1), 59-71.

3. Badis, D., Zoubir, B., Othmane, B., Boutoumi, H., Hamitouche H., and Aggoun, A. (2016). "Removal of methylene blue by adsorption onto retama raetam plant: Kinetics and equilibrium study." Chem. J. Moldova, 11, 74-83.

4. Boukhemkhem, A. and Rida, K. (2017). "Improvement adsorption capacity of methylene blue onto modified Tamazert kaolin." Adsorpt. Sci. Technol., 35(9-10), 753-773.

5. Buthelezi, P. S., Olaniran, O. A., and Pillay, B. (2012). "Textile Dye Removal from Wastewater Effluents Using Bioflocculants Produced by Indigenous Bacterial Isolates." Molecules, 17(12).

6. Caponi, N., Collazzo, G. C., Jahn, S. L., Dotto, G. L., Mazutti, M. A. and Foletto, E. L. (2017). "Use of Brazilian Kaolin as a Potential Low-cost Adsorbent for the Removal of Malachite Green from Colored Effluents." Mater. Res., 20, 14-22.

7. Chowdhury, S. and Saha, P. D. (2012). "Biosorption of methylene blue from aqueous solutions by a waste biomaterial: hen feathers." Appl. Water Sci., 2(3): 209-219.

8. Dai, H. and Huang, H. (2017). "Synthesis, characterization and properties of pineapple peel cellulose-g-acrylic acid hydrogel loaded with kaolin and sepia ink." Cellulose, 24(1), 69-84.

9. Ejder korucu, M., Gurses, A., Doğar, Ç., Sharma, S., and Açıkyıldız, M. (2015). “Removal of Organic Dyes from Industrial Effluents: An Overview of Physical and Biotechnological Applications.” 1-22.

10. He, K., Chen, G., Zeng, G., Chen, A., Huang, Z., Shi, J., Peng, M., Huang, T., and Hu, L. (2018). "Enhanced removal performance for methylene blue by kaolin with graphene oxide modification." J. Taiwan Inst. Chem. Eng., 89, 77-85.

11. He, K., Zeng, G., Chen, A., Huang, Z., Peng, M., Huang T., and Chen, G. (2019). "Graphene hybridized polydopamine-kaolin composite as effective adsorbent for methylene blue removal." Compos. Part B: Eng., 16,: 141-149.

12. Hemra, K. and Aungkavattana, P. (2016). "Effect of cordierite addition on compressive strength and thermal stability of metakaolin based geopolymer." Adv. Powder Technol., 27(3), 1021-1026.

13. Huang, Q., Liu, M., Chen, J., Wang, K., Xu, D., Deng, F., Huang, H., Zhang, X. and Wei, Y. (2016). "Enhanced removal capability of kaolin toward methylene blue by mussel-inspired functionalization." J. Mater. Sci., 51(17), 8116-8130.

14. Khairy, M., Ayoub, H. A., Rashwan, F. A. and Abdel-Hafez, H. F. (2018). "Chemical modification of commercial kaolin for mitigation of organic pollutants in environment via adsorption and generation of inorganic pesticides." Appl. Clay Sci., 153, 124-133.

15. Khan, T. A., Dahiya, S. and Ali, I. (2012). "Use of kaolinite as adsorbent: Equilibrium, dynamics and thermodynamic studies on the adsorption of Rhodamine B from aqueous solution." Appl. Clay Sci., 69, 58-66.

16. Lawal, I. A. and Moodley, B (2016). "Column, kinetic and isotherm studies of PAH (phenanthrene) and dye (acid red) on kaolin modified with 1-hexyl, 3-decahexyl imidazolium ionic liquid." J. Environ. Chem. Eng., 4(3), 2774-2784.

17. Mouni, L., Belkhiri, L., Bollinger, J.-C., Bouzaza, A., Assadi, A., Tirri, A., Dahmoune, F., Madani, K. and Remini, H. (2018). "Removal of Methylene Blue from aqueous solutions by adsorption on Kaolin: Kinetic and equilibrium studies." Appl. Clay Sci., 153, 38-45.

18. Naghsh, M. and Shams, K. (2017). "Synthesis of a kaolin-based geopolymer using a novel fusion method and its application in effective water softening." Appl. Clay Sci., 146, 238-245.

19. Nigiz, F. U. (2019). "Synthesis of a novel graphene–kaolin–alginate adsorbent for dye removal, and optimization of the adsorption by response surface methodology." Res. Chem. Intermediat., 45(7), 3739-3753.

20. Panda, A. K., Mishra, B. G., Mishra, D. K., and Singh, R. K. (2010). "Effect of sulphuric acid treatment on the physico-chemical characteristics of kaolin clay." Colloids Surf. A, 363(1), 98-104.

21. Rao, K. M., Mallikarjuna, B., Krishna Rao, K. S. V., Sudhakar, K., Rao, K. C. and Subha, M. C. S. (2013). "Synthesis and Characterization of pH Sensitive Poly (Hydroxy Ethyl Methacrylate-co-acrylamidoglycolic Acid) Based Hydrogels for Controlled Release Studies of 5-Fluorouracil." Int. J. Polym. Mater.,62(11), 565-571.

22. Rekik, S. B., Gassara, S., Bouaziz, J., Deratani, A., and Baklouti, S. (2017). "Development and characterization of porous membranes based on kaolin/chitosan composite." Appl. Clay Sci., 143, 1-9.

23. Rida, K., Bouraoui, S. and Hadnine, S. (2013). "Adsorption of methylene blue from aqueous solution by kaolin and zeolite." Appl. Clay Sci., 83-84, 99-105.

24. Robati, D. (2013). "Pseudo-second-order kinetic equations for modeling adsorption systems for removal of lead ions using multi-walled carbon nanotube." J. Nanostructure Chem., 3(1), 55.

25. Santos, E. C., Costa, L. S., Oliveira, E. S., Bessa, R. A., Freitas, A. D. L., Oliveira, C. P., Nascimento, R. F. and Loiola, A. R. (2018). "Al-MCM-41 Synthesized from Kaolin via Hydrothermal Route: Structural Characterization and Use as an Efficient Adsorbent of Methylene Blue." J. Braz. Chem. Soc., 29, 2378-2386.

26. Shirsath, S. R., Patil, A. P., Patil, R., Naik, J. B., Gogate, P. R., and Sonawane, S. H. (2013). "Removal of Brilliant Green from wastewater using conventional and ultrasonically prepared poly(acrylic acid) hydrogel loaded with kaolin clay: A comparative study." Ultrason. Sonochem., 20(3), 914-923.

27. Štengl, V. and Henych, J. (2013). "Feasible Synthesis of TiO2 Deposited on Kaolin for Photocatalytic Applications." Clay. Clay Miner., 61(3), 165-176.

28. Tang, Y., Wang, Q., Zhou, B., Ma, D., Ma, Z. and Zhu, L. (2015). "Synthesis of Sodium Alginate Graft Poly (Acrylic Acid-Co-Acrylamide)/ Kaolin Composite Hydrogel and the Study on Its Sorption of Rhodamine B." Polym. Polym. Compos., 23, 467-474.

29. Yagub, M. T., Sen, T. K., Afroze S. and Ang, H. M. (2014). "Dye and its removal from aqueous solution by adsorption: A review." Adv. Colloid Interface Sci., 209, 172-184.

30. Zaharia, C. and Suteu, D. (2012). “Textile Organic Dyes - Characteristics, Polluting Effects and Separation/Elimination Procedures from Industrial Effluents - A Critical Overview.” www.intechopen.com.



DOI: https://doi.org/10.22146/ajche.51457

Article Metrics

Abstract views : 3497 | views : 3142

Refbacks

  • There are currently no refbacks.


ASEAN Journal of Chemical Engineering  (print ISSN 1655-4418; online ISSN 2655-5409) is published by Chemical Engineering Department, Faculty of Engineering, Universitas Gadjah Mada.