Silylated MCM-41 Synthesized from RiceHusk

  • N Ketcome Department of Chemical Engineering, Faculty of Engineering, Thammasat University THAILAND
  • N Grisdanurak Department of Chemical Engineering, Faculty of Engineering, Thammasart University, THAILAND
Keywords: RH-MCM-41, CVOCs adsorption, hydrophobicity

Abstract

Mesoporous material, MCM-41, synthesized from rice husk (RH-MCM-41) was modified by loading silylating agent (either Trimethylchlorosilane (TMCS), Dimethyl- dichlorosilane (DMCS) or Phenyl-trichlorosilane (PTCS)) in different concentration (1-9 %wt), and aging time, varied from I, 6, 9 and 24 hr. Properties of samples were characterized by XRD, Nz adsorption, FfIR, and TPD and adsorption of water, hexane, and toluene. Chemical modification resulted smaller pore size average and less surface area of RH-MCM-41, from 2.9 to 2.2 nm and from 900 to 500 mZ/g, respectively. PTCS could affect RH-MCM-41 surface structure more than other two. Adsorption behavior of modified RH-MCM-41 was also reflected to comparatively higher hydrophobicity.

References

1. Assogna, A., Perego,G., Roggero,A., Sisto,R.,and Valentini,C. (1992). "Structureand gas permeability of silylated polyphenyleneoxide," J MembraneSci., 71,97-103.
2. Capel-Sanchez,M.C.,Barrio,L.,Campos-Martin, J.M.,Fierro,J.L.G. (2004) "Silylationand surface properties of chemically grafted hydrophobic silica,"J ColloidInterfSci.,277, 146-153.
3. Chen, C:f., Xiao,S-Q., and Davis,M.E. (1995)."Studies on Ordered mesoporous materials III.Comparison of MCM-41to mesoporous materials derived from kanemite," MicroporMater.,4, 1-20..
4. Firouzi,A., Kumar, D., Bull, L. M., Besier, T., Sieger, P., Huo, Q., Walker, S.A., Zasadzinski, J. A., Glinka, ., Nicol, J., Margolese, D. I., Stucky, G. D. and Chmelka, B. F. (1995). "CooperativeOrganization of Inorganic-Surfactant and Biomimetic Assemblies," Science., 267, 1138-1143.
5. Grisdanurak, N., Chiarakorn, S., and Wittayakun, J. (20.0.3)."Utilization of Mesoporous Molecular Seives Synthesized from Natural Source Rice Husk Silica to Chlorinated Volatile Organic Compounds (CVOCs) Adsorption," Korean J Chern Eng., 20. (5), 950.-955.
6. Imai,Y, and Oishi,Y (1989). "Novelsynthetic methodsforcondensationpolymersusing silylated nucleophilic monomers," REV ProgPolym Sci., 14, 173-193.
7. Jentys,o.A,Pham, N.H., Vinek,H., Englisch,M., and Lercher,J.A (1996). "Synthesisand char,acterizationof mesoporic materials containing highly dispersed cobalt" MicroporMater.,6, 13-17.
8. Liu,C., Naismith,N., and Economy,J. (20.04). "Advanced mesoporous organosilica material containing microporous D- cyclodextrinsfor the removal of humic acid fromwater."J ChromatogrA, 10.36, 113-118.
9. MariaChong, AS., Zhaoa, X. S., Kustedjo,T., and Qiao,S.Z.,(2004). "Functionalization of large-pore mesoporous silicas with organosilanes by direct synthesis," MicroporMesopor Mat., 72,33-42.
10. Nishiyama, N., Park, D-H., Egashira, Y., and Ueyama, K. (20.0.3). "Pore size distributionsofsilylatedmesoporoussilica MCM-48 membranes," Separ Purif Technol.,32, 127-132.
11. Park, D-H., Nishiyama, N., Egashira, Y., and Ueyama, K. (20.0.3). "Separation of organic/water mixtures with silylated MCM-48 silica membranes'" Micropor MesoporMat., 66, 69-76.
12. Ratanawong, 0., Grisdanurak, N., Kaewsrichan, L. (20.0.5).''Adsorption of oil emulsified in water with modified oil palm fruit fiber," P. S. J Sci Tech., XX, XX-XX(In press, ThaI).
13. Selvan, P., Bhatia, S. K., and Sonwane, C. G. (20.0.1). "Recent Advances in Processing and Characterization of Periodic Mesoporous MCM-41SilicateMolecular Sieves," Ind Eng Chern Res., 40, 3237- 3261.
14. Takei, T., Yamazaki, A., Watanabe, T., and Chikazawa,M.(1997)."WaterAdsorption Propertieson PorousSilicaGlassSurface Modified by TrimethylsilylGroups," J ColloidInterfSci., 188,409-414.
15. Yoshida,W.,and Cohen, Y (20.0.3)."Topological AFMcharacterizationofgraftpolymerized silica membranes," J Membrane ScL, 215, 249-264.
16. Zakaria, S., Hamzah, H., Murshidi,A J., and Deramen, M. (20.0.1). Chemical Modificationon lignocellulosicpolymeric oil palm empty fruitbunch for advanced material," Adv PolymTech.,20.(4),289- 295.
17. Zheng,S.,Gao,L.,and Guo,J. (20.01)."Synthesis and characterization of copper(II)- phenanthrolne complex grafted organic groups modifiedMCM-41,"MaterChem Phys., 71, 174-178.
Published
2006-12-31
How to Cite
Ketcome, N., & Grisdanurak, N. (2006). Silylated MCM-41 Synthesized from RiceHusk. ASEAN Journal of Chemical Engineering, 6(2), 91-97. Retrieved from https://dev.journal.ugm.ac.id/v3/AJChE/article/view/7668
Issue
Vol 6 No 2 (2006)
Section
Articles

Copyright holder for articles is ASEAN Journal of Chemical Engineering. Articles published in ASEAN J. Chem. Eng. are distributed under a Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0) license. 

Authors agree to transfer all copyright rights in and to the above work to the ASEAN Journal of Chemical Engineering Editorial Board so that the Editorial Board shall have the right to publish the work for non-profit use in any media or form. In return, authors retain: (1) all proprietary rights other than copyright; (2) re-use of all or part of the above paper in their other work; (3) right to reproduce or authorize others to reproduce the above paper for authors’ personal use or for company use if the source and the journal copyright notice is indicated, and if the reproduction is not made for the purpose of sale.