Enhancement Effect of Hydrogen Sulfide Over Metal Ion-Exchange Mesoporous Silicate FSM-16 for Acid Catalyzed Reactions

  • Lebong Andalaluna Deputy for Information, Energy, Material and Environmental Technology Agency for the Assessment and Application of Technology (BPPT), Indonesia
  • Masatoshi Sugioka Department of Applied Chemistry, Muroran Institute of Technology, Japan
Keywords: Metal-ion exchange, mesoporous silicate, hydrogen sulfide, activity enhancement

Abstract

The activity enhancement of metal ion-exchange mesoporous silicate FSM-16 (MeFSM-16) by sulfiding with hydrogen sulfide was studied using acid-catalyzed reactions, isomerization of I-butene, cis-2-butene and cyclopropane, as model reactions. It was revealed that the catalytic activities of MeFSM-16 for the acid-catalyzed reactions were remarkably enhanced after sulfiding with hydrogen sulfide. Moreover, it was observed that the optimum enhancement effect of hydrogen sulfide was obtained at the sulfiding temperature of 200°C. Infrared spectroscopic measurement of pyridine adsorption over sulfided MeFSM-16 showed that the activity enhancement of MeFSM-16 resulted in the generation of new Bronsted acid sites. Keywords: Metal ion-exchange, mesoporous silicate, hydrogen sulfide, and activity enhancement.

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Published
2005-12-31
How to Cite
Andalaluna, L., & Sugioka, M. (2005). Enhancement Effect of Hydrogen Sulfide Over Metal Ion-Exchange Mesoporous Silicate FSM-16 for Acid Catalyzed Reactions. ASEAN Journal of Chemical Engineering, 5(1), 76-83. Retrieved from https://dev.journal.ugm.ac.id/v3/AJChE/article/view/7637
Section
Articles