Enhanced Copper Ion Adsorption by Rice Husk and Sugarcane Bagasse-based Magnetic Nanoparticles Biocomposites

Iryanti Nata; Chairul Irawan; Muhammad Istnaeny Hudha; Aceng Lesti; Muhammad Hersandy Syarkani; Allam Naufal

doi:10.22146/ajche.12236

Iryanti Nata Department of Chemical Engineering, Lambung Mangkurat University, Banjarbaru 70714, Indonesia https://orcid.org/0000-0003-2610-4513
Chairul Irawan Department of Chemical Engineering, Lambung Mangkurat University, Banjarbaru 70714, Indonesia
Muhammad Istnaeny Hudha Department of Chemical Engineering, National Institute of Technology, Malang 65125, Indonesia
Aceng Lesti Department of Chemical Engineering, Lambung Mangkurat University, Banjarbaru 70714, Indonesia
Muhammad Hersandy Syarkani Department of Chemical Engineering, Lambung Mangkurat University, Banjarbaru 70714, Indonesia
Allam Naufal Department of Chemical Engineering, Lambung Mangkurat University, Banjarbaru 70714, Indonesia

DOI: https://doi.org/10.22146/ajche.12236

Keywords: Adsorbent, Bagasse, Biocomposites, Copper, Rice Husk

Abstract

Rice husk and sugarcane bagasse are biomass waste by-products of agriculture activities. High cellulose content makes them a potential material to develop. Biomass utilization is more interesting to develop due to its high cellulose content and nature abundance. Cellulose from rice husk and sugarcane bagasse is utilized as fiber in producing magnetic biocomposites. The Biocomposites can adsorb Cu(II) ions in aqueous solutions. A one-step solvothermal reaction was used to synthesize biocomposites. The amine functionalization on biocomposites was also studied for adsorption performance. The magnetic particle was generated on the surface of fiber and verified by XRD as Fe₃O₄. Amine group on biocomposites is also found on 570 cm^-1 and 1636 cm⁻¹ peaks for Fe-O bonds and N-H bending, respectively. Batch isothermal adsorption employing magnetic biocomposites has optimal conditions for Cu(II) ions adsorption at pH 5 for 60 minutes, with an adsorption capacity of 118.26 mg/g. The reusability of biocomposites for the next run showed a good performance at 3^rd repetitions with only a decrease in adsorption capacity of 8.81%. The rice husk and sugarcane bagasse-based magnetic nanoparticles biocomposites can adsorb Cu(II) ions and potential material to develop for wastewater treatment.

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