PENGARUH RUTE SINTESIS TERHADAP KEEFEKTIFAN PENGIKATAN GUGUS PDETA PADA SINTESIS Fe3O4@SiO2@PDETA

https://doi.org/10.22146/teknosains.36264

Susanto Susanto(1*), Ricka Prasdiantika(2)

(1) Fakultas Teknik, Universitas Pandanaran
(2) Fakultas Teknik, Universitas Pandanaran
(*) Corresponding Author

Abstract


Synthesis of Fe3O4@SiO2 modified with propyldiethylenetriamine (Fe3O4@SiO2@PDETA) with variation of synthesis routes have been investigated. Research was begun with synthesis of Fe3O4 using dispersion agent of trisodium citrate at coprecipitation system through stirring using ultrasonic wave. Coating magnetite with propyldiethylenetriamine modified silica was carried out through sol-gel process with two different mixing sequences of raw materials (two synthesis routes) with main materials of Fe3O4 synthesized, N-[3-(Trimethoxysilyl)propyl]-diethylenetriamine (TMSPDETA) and Na2SiO3. The products were characterized by fourier transform infrared (FTIR) spectrophotometer and scanning electron microscope-energy dispersive X-ray (SEM-EDX). Results indicate that Fe3O4@SiO2@PDETA has been synthesized succesfully. Fe3O4@SiO2@PDETA synthesized through route 1 (magnetite mixed with a mixture TMSPDETA and Na2SiO3) contains more propyldiethylenetriamine group than that of through route 2 (magnetite mixed with Na2SiO3 solution, then mixed with TMSPDETA)

Keywords


Effectiveness binding; Magnetite; Propyldiethylene-triamine; Silica modified; Synthesis routes

Full Text:

PDF


References

Aliev, F. G., M. A. Correa-Duarte, A. Mamedov, J. W. Ostrander, M. Giersig, L.M. Lix-Marzan, and N.A. Kotov. 1999. Layer-By-Layer Assembly of Core-Shell Magnetite Nanoparticles: Effect of Silica Coating on Interparticle Interactions and Magnetic Properties. Advanced Materials 11(12): 1006–1010.

Benavente, M. 2008. Adsorption of Metallic Ions onto Chitosan: Equilibrium and Kinetic Studies, Thesis, Department of Chemical Engineering and Technology. Royal Institute of Technology. Sweden.

Chiu, H., C. Liu, S. Chen, and S. Suen. 2009. Adsorptive Removal of Anionic Dye by Inorganic–Organic Hybrid Anion-Exchange Membranes. Journal of Membrane Science 337(1–2):282–290.

Coradin, T. dan P.J. Lopez. 2003. Biogenic Silica Patterning: Simple Chemistry or Substle Biology. ChemBioChem 4(4): 251–259.

Farimani, N.S., N.G. Roknabadi, and A. Kazemi. 2013. Study of Structural and Magnetic Properties of Super-paramagnetic Fe3O4/SiO2 Core–Shell Nanocomposites Synthe-sized with Hydrophilic Citrate-Modified Fe3O4 Seeds via A Sol–Gel Approach. Physica E 53: 207–216.

Fujiwara, K., A. Ramesh, T. Maki, H. Hasegawa, K. Ueda. 2007. Adsorption of platinum (IV), palladium (II) and gold (III) from aqueous solutions onto l-lysine modified crosslinked chitosan resin. Journal of Hazardous Materials. 146 (1-2): 39-50.

Haw, C.Y., Chia, C.H., Zakaria, S., Mohamed, and F., Radiman, S., Teh, C.H., Khiew, P.S., Chiu, W.S., and Huang, N.M., 2011, Morphological Studies of Randomized Dispersion Magnetite Nanoclusters Coated with Silica, Ceramics International 37(2): 451–464.

Hong, R.Y., J.H. Li, H.Z. Li, J. Ding, Y. Zheng, and D.G. Wei. 2008. Synthesis of Fe3O4 Nanoparticles without Inert Gas Protection Used as Precursors of Magnetic Fluids. Journal of Magnetism and Magnetic Materials 320(9): 1605–1614.

Jacintho, G.V.M., A.G. Brolo, P. Corio, P.A.Z. Suarez, and J.C. Rubim. 2009. Structural Investigation of MFe2O4 (M = Fe, Co) Magnetic Fluids. Journal of Physical Chemistry C 113(18): 7684–7691.

Khosroshahi, M.E., and L. Ghazanfari. 2010. Prepara-tion and Characterization of Silica-Coated Iron-Oxide Bionano-particles under N2 Gas. Physica E 42(6): 1824–1829.

Lin, Y., H. Chen, K. Lin, B. Chen, and C. Chiou. 2011. Application of Magnetic Particles Modified with Amino Groups to Adsorb Copper Ions in Aqueous Solution. Journal of Environmental Sciences 23: 44–50.

Liu, W., P. Yin, X. Liu, X. Dong, J. Zhang, and Q. Xu. 2013. Thermo Dynamics, Kinetics, and Isotherms Studies For gold(III) Adsorption Using Silica Functionalized by Diethylenetriamine Methy-lene Phosphonic Acid. Chemical Engineering Research and Design 91(12): 2748–2758.

Lo, S.F., Wang, S.Y., Tsai, M.J., Lin, L.D. 2012. Adsorption capacity and removal efficiency of heavy metal ions by Moso and Ma bamboo activated carbons. Chemical Engineering Research and Design 90(9): 1397-1406.

Mahmoud, M.E., M.M. El-Essawi, S.A. Kholeif and E.M.I. Fathalla. 2004. Aspects of Surface Modification, Structure characterization, Thermal Stability and Metal Selectivity properties of Silica Gel Phases-Immobilized-Amine Derivati-ves. Analytica Chimica Acta 525(1): 123–132.

Moussavi, G. and S. Talebi. 2012. Comparing the efficacy of a novel waste-based adsorbent with PAC for the simultaneous removal of chromium (VI) and cyanide from electroplating wastewater. Chemical Engineering Research and Design 90(7): 960-966.

Mulyati, E. 2014. Pelapisan Magnetit dengan Hibrida Merkapto-Silika untuk Adsorpsi Selektif Au(III) dari Sistem Multilogam Au(III)/Cu(II)/Ni(II). Tesis. Departemen Kimia FMIPA UGM. Yogyakarta.

Nguyen, N.V., J. Lee, S. Kim, M.K. Jha, K. Chung, J. Jeong. 2010. Adsorption of gold(III) from waste rinse water of semiconductor manufacturing industries using Amberlite XAD-7HP resin. Gold Bulletin, 43(3): 200-208.

Nuryono, N., N.M. Rosiati, B. Rusdiarso, S.C.W. Wibawa Sakti, and S. Tanaka. 2014. Coating of Magnetite with Mercapto Modified Rice Hull Ash Silica in a One-Pot Process. SpringerPlus 3(515):1-12.

Pavia, D.L., G.M. Lampman, and J.R. Vyvyan. 2001. Introduction to Spectroscopy, 4th Ed. Western Washington University. Washington.

Roldan, P.S., I.L. Alcântara, C.C.F. Padilha, and P.M. Padilha. 2005. Determination of Copper, Iron, Nickel And Zinc in Gasoline by FAAS after Sorption and Preconcen-tration on Silica Modifiedwith 2-Amino-tiazole Groups, Fuel, 84(2): 305-309.

Sales, J.A.A., and C. Airoldi. 2003. Epoxide Silylant Agent ethylenediamine Reaction Product Anchored on Silicagel–Thermodynamics of Cation–Nitrogen Interaction At solid/Liquid Interface. Journal of Non-Crystalline Solids 330(1-3):142-149.

Susanto, S., R. Prasdiantika, T.C.M. Bolle. 2016. Sintesis Nanomaterial Magnetit-Sitrat dan Pengujian Aplikasinya sebagai Adsorben Emas(III). Jurnal Teknosains 6(2):124-129.

Susanto, S., Prasdiantika, R., dan Bolle, T.C. 2016. Pengaruh Pelarut Terhadap Dispersi Partikel Fe3O4@Sitrat. Jurnal Sains Materi Indonesia, 17(4): 153–159.

Syukur, M. 2014. Sintesis Fe3O4/SiO2 Termodifikasi (N–(2–Aminoetil)–3– Aminopropil) untuk Adsorpsi-Desorpsi Anionik [AuCl4]-. Tesis. Departemen Kimia FMIPA UGM. Yogyakarta.

Voronkov, M.G. 1966. Silatranes: Intra-Complex Heterocyclic Compounds of Pentacoordinated Silicon. Pure and Applied Chemistry 13(1-2): 35–60.

Wang, H., H. Nakamura, Y. Yao, H. Maeda, and E. Abe. 2001. Effect of Solvents on the Preparation of Silica-Coated Magnetic Particles, Chemistry Letters 30(11): 1168–1169.

Zhang, Y., Q. Xu, S. Zhang, J. Liu, J. Zhou, H. Xu, H. Xiao, and J. Li. 2013. Preparation of Thiol-Modified Fe3O4@SiO2 Nanoparticles and Their Application for Gold Recovery From Dilute Solution. Separation and Purification Technology 116: 391–397.



DOI: https://doi.org/10.22146/teknosains.36264

Article Metrics

Abstract views : 2654 | views : 3749

Refbacks

  • There are currently no refbacks.


Bookmark and Share


Copyright (c) 2018 Susanto Susanto, Ricka Prasdiantika

Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.




Copyright © 2024 Jurnal Teknosains     Submit an Article        Tracking Your Submission

Editorial Policies       Publishing System       Copyright Notice       Site Map       Journal History      Visitor Statistics     Abstracting & Indexing