Screen Printed-Carbon Electrode Modifikasi Bismut untuk Analisis Kadmium dengan Voltametri Siklik

https://doi.org/10.22146/ijeis.54138

Novianti Novianti(1*), R V Manurung(2), Arifin Arifin(3)

(1) Departemen Fisika, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Hasanuddin
(2) Pusat Penelitian Elektronika dan Instrumentasi, Lembaga Ilmu Pengetahuan Indonesia
(3) Departemen Fisika, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Hasanuddin
(*) Corresponding Author

Abstract


Cadmium (Cd) is a heavy metal that has high toxicity. Cadmium levels need to be considered in an environment that can accumulate and can poison all biotic components. In this research measurements of cadmium metal using bismuth-modified carbon screen electrode  used cyclic voltammetry method. The parameters considered are the resolution of the comparative electrodes and the voltage produced from variations in cadmium concentration. The test results prove the stability of three sensors each at a voltage of 3.3 - 4.6 mV, 9.3-11.4 mV, and 27.4 - 29.8 mV. While the results of the cyclic voltammetry characterization test vary depending on the concentration of cadmium. Concentrations of 0.5-100 ng / mL produce an oxidation peak at a current of 2.03 x 10-5 - 5.00 x 10-5 A. These results show a directly proportional relationship between the cadmium concentration and the resulting current.

Keywords


screen printing; carbon electrode; cadmium; bismuth; cyclic voltammetry

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References

[1] A. Ourari, F. Tennah, R. R. Rosas, D. Aggoun, E. Morallon, “Bentonite modified carbon paste electrode as a selective electrochemical sensor for the detection of cadmium and lead in aqueous solution”, International Journal of Electrochemical Science, vol. 13, pp. 1683-1699, 2018.

[2] N. K. T. Martuti, H. A. Sanjivanie, S Ngabekti, “Bioakumulasi Kadmium Pada Ikan Bandeng di Tambak Dukuh Tapak Semarang”, Jurnal MIPA, vol. 39, no. 2, pp. 92-97, 2016.

[3] T. Wijayanti dan D. E. G. Lestari, “Bioremediasi Limbah Tercemar Kadmium (Cd) pada Perairan di Kabupaten Pasuruan Menggunakan Bakteri Indigen Secara Ex-Situ”, Jurnal Pena Sains, vol. 4, no. 2, pp. 114-123, 2017.

[4] S. Chaiyo, E. Mehmeti, K. Zagar, W. Siangproh, O. Chailapakul, K. Kalcher, “Electrochemical Sensors for The Simultaneous Determination of Zinc, Cadmium, and Lead Using a Nafion/Ionic Liquid/Graphene Composite Modified Screen-Printed Carbon Electrode”, Analytica Chimica Acta, 2016.

[5] Irdhawati, E. Sahara, I. W. Hermawan, “Teknik Voltametri Pelucutan Anodik Untuk Penentuan Kadar Logam Cu (II) Pada Air Laut Pelabuhan Benoa”, Jurnal Kimia, vol. 10, no. 1, pp. 81-88, 2016.

[6] Irdhawati, H. Suyanto, P. Y. Andani, “Penggunaan Elektroda Pasta Carbon Termodifikasi Zeolit Untuk Analisis Logam Cu Secara Voltametri Pelucutan Anodik”, ALCHEMY Jurnal Penelitian Kimia, vol. 13, no. 1, pp. 1-16, 2017.

[7] E. Rohaeti, W. T. Wahyuni, M. A. Rohman, “Modifikasi Screen Printed Carbon Electrode dengan Polimer Tercetak Molekul (MIP) dan Aplikasinya untuk Deteksi Glutation”, Analit: Analytical and Environmental Chemistry, vol. 3, no. 1, pp. 47-60, 2018.

[8] S. Rana, S. K. Mittal, N. Singh, J. Singh, C. E. Banks, “Schiff base modified screen printed electrode for selective determination of Aluminium (III) at trace level”, Sensors and Actuators B, pp. 1-37, 2016.

[9] B. B. Yucebas, Y. T. Yaman, G. Bolat, E. Ozgur, L. Uzun, S. Abaci, “Molecular Imprinted Polymer Based Electrochemical Sensor for Selective Detection of Paraben”, Sensors and Actuators: B, Chemical 2019.

[10] Z. Lu, J. Zhang, W. Dai, X. Lin, J. Ye, J. Ye, “A screen-printed carbon electrode modified with a bismuth film and gold nanoparticles for simultaneous stripping voltammetric determination of Zn(II), Pb(II), and Cu(II)”, Microchim Acta, vol. 184, pp. 4731-4740, 2017.

[11] D. Maity, Minitha C. R., Rajendra, K. R. T., “Glucose oxidase immobilized amine terminated multiwall carbon nanotubes/reduced grapheme oxide/polyanilinegold nanoparticles modified screen-printed carbon electrode for hoghly sensitive amperometric glucose detection”, Materials Science & Engineering C, vol. 105, pp. 1-10, 2019.

[12] G. Ibanez-Redin, D. Wilson, D. Goncalves, O.N. Oliveira Jr, “Low-cost screen-printed electrodes based on electrochemically reduced graphene oxide-carbon black nanocomposites for dopamine, epinephrine and parachetamol detection”, Journal of Colloid and Interface Science, pp. 1-22, 2017. [] A. A. Kava, C. Beardsley, J. Hofstetter, C. S. Henry, “Disposable Glassy Carbon Stencil Printed Electrodes for Trace Detection of Cadmium and Lead”, Analytica Chimica Acta, pp. 1-33, 2019.

[13] L. Durai dan S. Badhulika, “Ultra-selektive, trace level detection of As3+ ions in blood samples using PANI coated BiVO4 modified SPCE via differential pulse anode stripping voltammetry”, Materials Science & Engineering C, pp. 1-31, 2020.

[14] G. Ibanez-Redin, D. Wilson, D. Goncalves, O.N. Oliveira Jr, “Low-cost screen-printed electrodes based on electrochemically reduced graphene oxide-carbon black nanocomposites for dopamine, epinephrine and parachetamol detection”, Journal of Colloid and Interface Science, pp. 1-22, 2017.

[15] S. Zhou, X. Guo, L. Meng, J. Cui, J. Li, X. Yuan, D. Wu, “A miniature electrochemical detection system based on GOQDs/MWCNTs/SPCE* for determination the purine in cells”, Analytical Biochemistry, vol. 577, pp. 67-72, 2019.



DOI: https://doi.org/10.22146/ijeis.54138

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