* Corresponding Author
Synthesis, Structure, Antibacterial Activity, and Hirshfeld Surface Analysis of Complex [Co(4-ampy)4(NCS)2]·CO2
https://doi.org/10.22146/ijc.90585 Linggar Agil Savitri(1), Faaza'izzahaq Setta Putra(2), Sutandyo Dwija Laksmana(3), Dewi Mariyam(4), I Wayan Dasna(5*)
(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Malang, Jl. Semarang No. 5, Malang 65145, Indonesia
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Malang, Jl. Semarang No. 5, Malang 65145, Indonesia
(3) Center of Advanced Material for Renewable Energy, Universitas Negeri Malang, Jl. Semarang No. 5, Malang 65145, Indonesia
(4) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Malang, Jl. Semarang No. 5, Malang 65145, Indonesia
(5) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Malang, Jl. Semarang No. 5, Malang 65145, Indonesia; Center of Advanced Material for Renewable Energy, Universitas Negeri Malang, Jl. Semarang No. 5, Malang 65145, Indonesia
(*) Corresponding Author
Abstract
The [Co(4-ampy)4(NCS)]2·CO2 complex compound was successfully synthesized using the reflux method from the reaction between CoCl2·6H2O, 4-aminopyridine, and KSCN in methanol solvent for 6 h at 64 °C. The synthesized compound is a dark purple cube-shaped crystal with a melting point of 209 °C. FTIR test showed the presence of isothiocyanate anion at C=N stretching vibration wavenumber 1633 cm−1, C–N vibration on amine group belonging to 4-aminopyridine ligand at 1217 cm−1, and C=N vibration of pyridine aromatic group at 1334 cm−1. Single crystal X-ray diffraction data refinement results show the complex compound has octahedral geometry in a cubic lattice with space group Pn̄3n with lattice parameters a = b = c = 16.426(3) Å and α = β = γ = 90°. According to the crystal data, there was one molecule of CO2 in the crystal packing of the complex. Hirshfeld surface analysis showed the major interaction contributions from C⋯H/H⋯C, H⋯H, S⋯H/H⋯S, and O⋯H/H⋯O. The antibacterial activity test results showed that the activity of the synthesized complex was more active against Staphylococcus aureus but less effective against Escherichia coli.
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DOI: https://doi.org/10.22146/ijc.90585
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