* Corresponding Author
Ferrate(VI) Synthesis Using Fe(OH)3 from Waste Iron Electrolysis and Its Application for the Removal of Metal Ions and Anions in Water
https://doi.org/10.22146/ijc.64824 Gunawan Gunawan(1*), Abdul Haris(2), Nor Basid Adiwibawa Prasetya(3), Eka Pratista(4), Azis Amrullah(5)
(1) Department of Chemistry, Faculty of Sciences and Mathematics, Diponegoro University, Jl. Prof. H. Soedarto, SH, Tembalang, Semarang 50275, Indonesia
(2) Department of Chemistry, Faculty of Sciences and Mathematics, Diponegoro University, Jl. Prof. H. Soedarto, SH, Tembalang, Semarang 50275, Indonesia
(3) Department of Chemistry, Faculty of Sciences and Mathematics, Diponegoro University, Jl. Prof. H. Soedarto, SH, Tembalang, Semarang 50275, Indonesia
(4) Department of Chemistry, Faculty of Sciences and Mathematics, Diponegoro University, Jl. Prof. H. Soedarto, SH, Tembalang, Semarang 50275, Indonesia
(5) Department of Chemistry, Faculty of Sciences and Mathematics, Diponegoro University, Jl. Prof. H. Soedarto, SH, Tembalang, Semarang 50275, Indonesia
(*) Corresponding Author
Abstract
Ferrate(VI) salt is an effective oxidant and coagulant for water treatment and removal of metal ions. This study demonstrates a new approach to processing metal ions and anions in water by Fe(VI) through Fe(III) obtained from the electrolysis of waste iron transformer. The electrolysis was successfully carried out in the Na2SO4 electrolyte using waste iron and zinc plates as anode and cathode, respectively. Fe(III) electrolysis results through the characterization of FTIR and XRD indicate compliance with Fe(OH)3 standards. Synthesis of ferrate was carried out by adding Fe(III) from electrolysis with NaOCl in alkaline conditions. The formed ferrate solution shows a purple color with a typical maximum wavelength of 505 nm. Furthermore, the ferrate obtained is used to remove metal ions (Fe(III), Cu(II), Zn(II), Mg(II), Pb(II)) and anions (sulfate, nitrate, and carbonate) in water with pH variations. Ferrate treatment filtrate was analyzed using AAS for metal ions, while sulfate, nitrate, and carbonate anions used UV-Vis spectrophotometry, turbidimetry, and titration methods. The results showed that ferrate effectively eliminates metal ions and anions in water with optimum pH 6. The mechanism of heavy metal removal by ferrate(VI) can be explained by ionic bonding and adsorption.
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[1] Chávez-Guajardo, A.E., Medina-Llamas, J.C., Maqueira, L., Andrade, C.A.S., Alves, K.G.B., and de Melo, C.P., 2015, Efficient removal of Cr(VI) and Cu(II) ions from aqueous media by use of polypyrrole/maghemite and polyaniline/maghemite magnetic nanocomposites, Chem. Eng. J., 281, 826–836.
[2] Sharma, V.K., Chen, L., and Zboril, R., 2015, Review on high valent Fe(VI) (Ferrate): A sustainable green oxidant in organic chemistry and transformation of pharmaceuticals, ACS Sustainable Chem. Eng., 4 (1), 18–34.
[3] Munyengabe, A., and Zvinowanda, C., 2019, Production, characterization and application of ferrate(VI) in water and wastewater treatments, Braz. J. Anal. Chem., 6 (25), 40–57.
[4] Barışçı, S., 2017, The disinfection and natural organic matter removal performance of electro-synthesized ferrate(VI), J. Water Process Eng., 20, 84–89.
[5] McBeath, S.T., Wilkinson, D.P., and Graham, N.J.D., 2020, Exploiting water contaminants: In-situ electrochemical generation of ferrates using ambient raw water iron (Fe2+), J. Environ. Chem. Eng., 8 (4), 103834.
[6] Majid, D., and Kim, I.K., 2018, Degradation of toluene by liquid ferrate(VI) and solid ferrate(VI) in aqueous phase, J. Environ. Eng., 144 (9), 04018093.
[7] Karelius, K., and Asi, N.B., 2016, Sintesis ferrat (FeO42–) dari Fe(NO3)3 dan NaOCl sebagai pendagradasi methylene blue, Sains dan Terapan Kimia, 10 (1), 1–7.
[8] Malik, S.N., Ghosh, P.C., Vaidya, A.N., Waindeskar, V., Das, S., and Mudliar, S.N., 2017, Comparison of coagulation, ozone and ferrate treatment processes for color, COD and toxicity removal from complex textile wastewater, Water Sci. Technol., 76 (5), 1001–1010.
[9] Soni, B.D., Patel, U.D., Agrawal, A., and Ruparelia, J.P., 2017, Application of BDD and DSA electrodes for the removal of RB 5 in batch and continuous operation, J. Water Process Eng., 17, 11–21.
[10] Song, Y., Men, B., Wang, D., and Ma, J., 2017, Online batch production of ferrate with a chemical method and its potential application for greywater recycling with Al(III) salt, J. Environ. Sci., 52, 1–7.
[11] Liu, C., Zhou, Z., Yuan, B., Liu, S., Li, F., and Sharma, V.K., 2018, Synthesis of ferrate(VI) in two cathodes and one anode cell: Enhanced efficiency and treatment of thiocyanate in wastewater, J. Environ. Eng., 144 (10), 04018105.
[12] Zeng, F., Chen, C., and Huang, X., 2020, Enhanced electro-generated ferrate using Fe(0)-plated carbon sheet as an anode and its online utilization for removal of cyanide, Chemosphere, 241, 125124.
[13] Micic, R., Jokic, A., Simonovic, R., Arsic, B., Mitic, M., Galonja-Coghill, T., Cekerevac, M., and Nikolic-Bujanovic, L., 2019, Application of electrochemically synthesized ferrates(VI) for the removal of Th(IV) from natural water samples, J. Water Chem. Technol., 41 (2), 101–104.
[14] Prucek, R., Tuček, J., Kolařík, J., Hušková, I., Filip, J., Varma, R.S., Sharma, V.K., and Zbořil, R., 2015, Ferrate(VI)-prompted removal of metals in aqueous media: mechanistic delineation of enhanced efficiency via metal entrenchment in magnetic oxides, Environ. Sci. Technol., 49 (4), 2319–2327.
[15] Barişçi, S., Ulu, F., Särkkä, H., Dimoglo, A., and Sillanpää, M., 2014, Electrosynthesis of ferrate(VI) ion using high purity iron electrodes: Optimization of influencing parameters on the process and investigating its stability, Int. J. Electrochem. Sci., 9, 3099–3117.
[16] Vidal, J., Espinoza, C., Contreras, N., and Salazar, R., 2017, Elimination of industrial textile dye by electrocoagulation using iron electrodes, J. Chil. Chem. Soc., 62 (2), 3519–3524.
[17] van der Grift, B., Behrends, T., Osté, L.A., Schot, P.P., Wassen, M.J., and Griffioen, J., 2016, Fe hydroxyphosphate precipitation and Fe(II) oxidation kinetics upon aeration of Fe(II) and phosphate-containing synthetic and natural solutions, Geochim. Cosmochim. Acta, 186, 71–90.
[18] Singh, K., and Kumar, A., 2019, Kinetics of complex formation of Fe(III) with caffeic acid: Experimental and theoretical study Kinetics of complex formation of Fe(III) with caffeic acid: Experimental and theoretical study, Spectrochim. Acta, Part A, 211, 148–153.
[19] Macera, L., Taglieri, G., Daniele, V., Passacantando, M., and D'Orazio, F., 2020, Nano-sized Fe(III) oxide particles starting from an innovative and eco-friendly synthesis method, Nanomaterials, 10 (2), 323.
[20] Zhu, B.S., Jia, Y., Jin, Z., Sun, B., Luo, T., Kong, L.T., and Liu, J.H., 2015, A facile precipitation synthesis of mesoporous 2-line ferrihydrite with good fluoride removal properties, RSC Adv., 5 (103), 84389–84397.
[21] Yan, F., Zhang, S., Zhang, X., Li, C., Zhu, C., Zhang, X., and Chen, Y., 2018, Growth of CoFe2O4 hollow nanoparticles on graphene sheets for high-performance electromagnetic wave absorbers, J. Mater. Chem. C, 6 (47), 12781–12787.
[22] Gunawan, G., Haris, A., Widodo, D.S., Suyati, L., and Septina, W., 2020, Degradation of methylene blue using cadmium sulfide photoanode in photofuel cell system with variation of electrolytes, Indones. J. Chem., 21 (1), 97–107.
[23] Cheung, P.C.W., Williams, D.R., Barrett, J., Barker, J., Kirk, D.W., Barrett, D.R., Barker, J., Kirk, J., Paeng, K.J., and Pettignano, A., 2021, On the origins of some spectroscopic properties of “purple iron” (the tetraoxoferrate(VI) ion) and its Pourbaix safe-space, Molecules, 26 (17), 5266.
[24] Luo, Z., Strouse, M., Jiang, J.Q., and Sharma, V.K., 2011, Methodologies for the analytical determination of ferrate(VI): A Review, J. Environ. Sci. Health, Part A: Toxic/Hazard. Subst. Environ. Eng., 46 (5), 453–460.
[25] Bartzatt, R., 2016, Reduction of metal ion species in contaminated water by utilizing potassium ferrate (K2FeO4) treatment, Br. J. Environ. Clim. Change, 6 (4), 227–235.
[26] Talaiekhozani, A., Talaei, M.R., and Rezania, S., 2017, An overview on production and application of ferrate(VI) for chemical oxidation, coagulation and disinfection of water and wastewater, J. Environ. Chem. Eng., 5 (2), 1828–1842.
[27] Nguema, P.F., and Jun, M., 2016, Application of ferrate(VI) as disinfectant in drinking water treatment processes: A review, Int. J. Microbiol. Res., 7 (2), 53–62.
[28] Dong, S., Mu, Y., and Sun, X., 2019, Removal of toxic metals using ferrate(VI): A review, Water Sci. Technol., 80 (7), 1213–1225.
[29] Zhang, B.L., Qiu, W., Wang, P.P., Liu, Y.L., Zou, J., Wang, L., and Ma, J., 2020, Mechanism study about the adsorption of Pb(II) and Cd(II) with iron-trimesic metal-organic frameworks, Chem. Eng. J., 385, 123507.
[30] Zhao, J., Wang, Q., Fu, Y., Peng, B., and Zhou, G., 2018, Kinetics and mechanism of diclofenac removal using ferrate(VI): Roles of Fe3+, Fe2+, and Mn2+, Environ. Sci. Pollut. Res., 25 (23), 22998–23008.
[31] Laksono, F.B., and Kim, I.K., 2015, Application of in situ liquid ferrate(VI) for 2-bromophenol removal, J. Korean Soc. Water Wastewater, 29 (6), 685–692.
[32] Filip, J., Yngard, R.A., Siskova, K., Marusak, Z., Ettler, V., Sajdl, P., Sharma, V.K., and Zboril, R., 2011, Mechanisms and efficiency of the simultaneous removal of metals and cyanides by using ferrate(VI): Crucial roles of nanocrystalline iron(III) oxyhydroxides and metal carbonates, Chem. Eur. J., 17 (36), 10097–10105.
[33] Sharma, V.K., and Virender, K., 2011, Oxidation of inorganic contaminants by ferrates (VI, V, and IV)-kinetics and mechanisms: A review, J. Environ. Manage., 92 (4), 1051–1073.
[34] Wang, H., Liu, Y., and Jiang, J.Q., 2016, Reaction kinetics and oxidation product formation in the degradation of acetaminophen by ferrate(VI), Chemosphere, 155, 583–590.
DOI: https://doi.org/10.22146/ijc.64824
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