A Fixed-Bed Column Study for Removal of Organic Dyes from Aqueous Solution by Pre-Treated Durian Peel Waste

https://doi.org/10.22146/ijc.39712

Nguyen Thi Thuong(1), Nguyen Thi Tuyet Nhi(2), Vo Thi Cam Nhung(3), Hoang Ngoc Bich(4), Bui Thi Phuong Quynh(5), Long Giang Bach(6*), Nguyen Duy Trinh(7)

(1) NTT Hi-Technology Institute, Nguyen Tat Thanh University, Ho Chi Minh City 755000, Vietnam
(2) Faculty of Food, Chemical & Environmental Sciences, Nguyen Tat Thanh University, Ho Chi Minh City 755000, Vietnam
(3) Faculty of Food, Chemical & Environmental Sciences, Nguyen Tat Thanh University, Ho Chi Minh City 755000, Vietnam
(4) NTT Hi-Technology Institute, Nguyen Tat Thanh University, Ho Chi Minh City 755000, Vietnam
(5) Faculty of Chemical Technology, Ho Chi Minh City University of Food Industry, Ho Chi Minh City 705800, Vietnam
(6) NTT Hi-Technology Institute, Nguyen Tat Thanh University, Ho Chi Minh City 755000, Vietnam
(7) NTT Hi-Technology Institute, Nguyen Tat Thanh University, Ho Chi Minh City 755000, Vietnam
(*) Corresponding Author

Abstract


A number of harmful effects on the ecosystem, the life of humankind, and living species caused by dye-contaminated wastewater have urged the development for an efficient and cost-efficient treatment method for colored effluents. The cellulose-based adsorbents have been considered as a facile and efficient approach to remove hazardous pollutants because of the abundance of inexpensive agricultural wastes in Viet Nam. This study aims to investigate the elimination of methylene blue (MB) and crystal violet (VL) from wastewater using a fixed-bed column of pre-treated durian peel. Examined variables in the process are bed depths (2–6 cm), flow rate (5–20 mL/min), and influent dye concentrations (200–600 mg/L). The highest adsorption amount of pre-treated DP was 235.80 mg/g and 527.64 mg/g, respectively, on a 600 mg/L of methylene blue and crystal violet achieved within a bed height of 4 cm and a flow rate of 10 mL/min. Accordingly, the breakthrough curves were constructed and modeled using the relevant theoretical models under the effects of different experimental conditions. Pre-treated durian peel was found to exhibit high adsorption capacity for cationic dye in an initial concentration of 200–600 mg/L with complete removal being obtained.

Keywords


adsorption; durian peel; fixed-bed column; methylene blue; crystal violet

Full Text:

Full Text PDF


References

[1] Kurniawan, T.A., Chan, G.Y.S., Lo, W.-H., and Babel, S., 2006, Physico-chemical treatment techniques for wastewater laden with heavy metals, Chem. Eng. J., 118 (1-2), 83–98.

[2] Ahmad, A., Mohd-Setapar, S.H., Chuong, C.S., Khatoon, A., Wani, W.A., Kumar, R., and Rafatullah, M., 2015, Recent advances in new generation dye removal technologies: novel search of approaches to reprocess waste water, RSC Adv., 5, 30801–30818.

[3] De Gisi, S., Lofrano, G., Grassi, M., and Notarnicola, M., 2016, Characteristics and adsorption capacities of low-cost sorbents for wastewater treatment: A review, Sustainable Mater. Technol., 9, 10–40.

[4] Bhatnagar, A., Sillanpää, M., and Witek-Krowiak, A., 2015, Agricultural waste peels as versatile biomass for water purification – A review, Chem. Eng. J., 270, 244–271.

[5] Ali, I., Asim, M., and Khan, T.A., 2012, Low cost adsorbents for the removal of organic pollutants from wastewater, J. Environ. Manage., 113, 170–183.

[6] Gautam, R.K., Mudhoo, A., Lofrano, G., and Chattopadhyaya, M.C., 2014, Biomass-derived biosorbents for metal ions sequestration: Adsorbent modification and activation methods and adsorbent regeneration, J. Environ. Chem. Eng., 2 (1), 239–259.

[7] Barakat, M.A., 2011, New trends in removing heavy metals from industrial wastewater, Arabian J. Chem., 4 (4), 361–377.

[8] Subhadrabandhu, S., and Ketsa, S., 2002, Durian, King of Tropical Fruit, Postharvest Biology and Technology Daphne Brasell Associates, Thordon, Wellington, New Zealand, 117–178.

[9] Tham, Y.J., Latif, P.A., Abdullah, A.M., Shamala-Devi, A., and Taufiq-Yap, Y.H., 2011, Performances of toluene removal by activated carbon derived from durian shell, Bioresour. Technol., 102 (2), 724–728.

[10] Chandra, T.C., Mirna, M.M., Sunarso, J., Sudaryanto, Y., and Ismadji, S., 2009, Activated carbon from durian shell: Preparation and characterization, J. Taiwan Inst. Chem. Eng., 40 (4), 457–462.

[11] Chandra, T.C., Mirna, M.M., Sudaryanto, Y., and Ismadji, S., 2007, Adsorption of basic dye onto activated carbon prepared from durian shell: Studies of adsorption equilibrium and kinetics, Chem. Eng. J., 127 (1-3), 121–129.

[12] Ahmad, M.A., Ahmad, N., and Bello, O.S., 2014, Modified durian seed as adsorbent for the removal of methyl red dye from aqueous solutions, Appl. Water Sci., 5 (4), 407–423.

[13] Kurniawan, A., Sisnandy, V.O.A., Trilestari, K., Sunarso, J., Indraswati, N., and Ismadji, S., 2011, Performance of durian shell waste as high capacity biosorbent for Cr(VI) removal from synthetic wastewater, Ecol. Eng., 37 (6), 940–947.

[14] Hameed, B.H., and Hakimi, H., 2008, Utilization of durian (Durio zibethinus Murray) peel as low cost sorbent for the removal of acid dye from aqueous solutions, Biochem. Eng. J., 39 (2), 338–343.

[15] Foo, K.Y., and Hameed, B.H., 2012, Textural porosity, surface chemistry and adsorptive properties of durian shell derived activated carbon prepared by microwave assisted NaOH activation, Chem. Eng. J., 187, 53–62.

[16] Nuithitikul, K., Srikhun, S., and Hirunpraditkoon, S., 2010, Kinetics and equilibrium adsorption of Basic Green 4 dye on activated carbon derived from durian peel: Effects of pyrolysis and post-treatment conditions, J. Taiwan Inst. Chem. Eng., 41 (5), 591–598.

[17] Mallampati, R., Xuanjun, L., Adin, A., and Valiyaveettil, S., 2015, Fruit peels as efficient renewable adsorbents for removal of dissolved heavy metals and dyes from water, ACS Sustainable Chem. Eng., 3, 1117–1124.

[18] Martin, M.A., Siles, J.A., Chica, A.F., and Martin, A., 2010, Biomethanization of orange peel waste, Bioresour. Technol., 101 (23), 8993–8999.

[19] Nhung, N.T.H., Quynh, B.T.P., Thao, P.T.T., Bich, H.N., and Giang, B.L., 2018, Pretreated fruit peels as adsorbents for removal of dyes from water, IOP Conf. Ser. Earth Environ. Sci., 159, 1–8.

[20] Goswami, M., and Phukan, P., 2017, Enhanced adsorption of cationic dyes using sulfonic acid modified activated carbon, J. Environ. Chem. Eng., 5 (4), 3508–3517.

[21] Penjumras, P., Rahman, R.B.A., Talib, R.A., and Abdan, K., 2014, Extraction and characterization of cellulose from durian rind, Agric. Agric. Sci. Procedia, 2, 237–243.

[22] Salazar-Rabago, J.J., Leyva-Ramos, R., Rivera-Utrilla, J., Ocampo-Perez, R., and Cerino-Cordova, F.J., 2017, Biosorption mechanism of Methylene Blue from aqueous solution onto White Pine (Pinus durangensis) sawdust: Effect of operating conditions, Sustainable Environ. Res., 27 (1), 32–40.

[23] Yagub, M.T., Sen, T.K., Afroze, S., and Ang, H.M., 2014, Fixed-bed dynamic column adsorption study of methylene blue (MB) onto pine cone, Desalin. Water Treat., 55 (4), 1026-1039.

[24] Guarín, J.R., Moreno-Pirajan, J.C., and Giraldo, L., 2018, Kinetic study of the bioadsorption of methylene blue on the surface of the biomass obtained from the Algae D. antarctica, J. Chem., 2018, 2124845.

[25] Santhi, T., Manonmani, S., Vasantha, V.S., and Chang, Y.T., 2016, A new alternative adsorbent for the removal of cationic dyes from aqueous solution, Arabian J. Chem., 9 (Suppl. 1), 466–474.

[26] Mohammed, N., Grishkewich, N., Waeijen, H.A., Berry, R.M., and Tam, K.C., 2016, Continuous flow adsorption of methylene blue by cellulose nanocrystal-alginate hydrogel beads in fixed bed columns, Carbohydr. Polym., 136, 1194–1202.

[27] El Messaoudi, N., El Khomri, M., Dbik, A., Bentahar, S., Lacherai, A., and Bakiz, B., 2016, Biosorption of Congo red in a fixed-bed column from aqueous solution using jujube shell: Experimental and mathematical modeling, J. Environ. Chem. Eng., 4 (4), 3848–3855.

[28] Yu, J., Zhu, J., Feng, L., Cai, X., Zhang, Y., and Chi, R., 2015, Removal of cationic dyes by modified waste biosorbent under continuous model: Competitive adsorption and kinetics, Arabian J. Chem., In press.

[29] Sajab, M.S., Chia, C.H., Zakaria, S., and Sillanpää, M., 2015, Fixed-bed column studies for the removal of cationic and anionic dyes by chemically modified oil palm empty fruit bunch fibers: Single- and multi-solute systems, Desalin. Water Treat., 55 (5), 1372–1379.



DOI: https://doi.org/10.22146/ijc.39712

Article Metrics

Abstract views : 4985 | views : 3614


Copyright (c) 2019 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 


Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web
Analytics View The Statistics of Indones. J. Chem.