Study on Growth Mechanism of Cu Nanowires and Its Application as Transparent Conducting Electrode
Dedi Mardiansyah(1*), Kuwat Triyana(2), Harsojo Harsojo(3)
(1) Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(2) Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(3) Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(*) Corresponding Author
Abstract
Cu nanowires (CuNWs) were synthesized in an aqueous solution at low temperature using ethylenediamine (EDA) as a capping agent and hydrazine as a reducing agent. This study investigated the growth of mechanism CuNWs and fabricated the transparent conducting electrode. For the growth mechanism of CuNWs, the study was conducted with an optical microscope, scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD). The performance of the transparent conducting electrode was studied with UV-Vis spectrometer and IV meters. CuNWs growth from Cu nanoparticles (CuNPs) in the solution. Transparent conducting electrode gave a sheet resistance of 48.8 Ohm/sq and the transmittance of 52.63%. The understanding of the growing mechanism of Cu nanowires is important for the development of CuNWs for alternative application as a transparent conducting electrode.
Keywords
Full Text:
Full Text PDFReferences
[1] Kim, M.J., Flowers, P.F., Stewart, I.E., Ye, S., Baek, S., Kim, J.J., and Wiley, B.J., 2017, Ethylenediamine promotes Cu nanowire growth by inhibiting oxidation of Cu(111), J. Am. Chem. Soc., 139 (1), 277−284.
[2] Sannicolo, T., Lagrange, M., Cabos, A., Celle, C., Simonato, J., and Bellet. D., 2016, Metallic nanowire-based transparent electrodes for next generation flexible devices : A review, Small, 12 (44), 6052–6075.
[3] Ye, S., Rathmell, A.R., Chen, Z., Stewart, I.E., and Wiley. B.J., 2014, Metal nanowire networks: The next generation of transparent conductors, Adv. Mater., 26 (39), 6670–6687.
[4] Zhai, H., Wang, R., Wang, X., Cheng, Y., Shi, L., and Sun, J., 2016, Transparent heaters based on highly stable Cu nanowire films, Nano Res., 9 (12), 3924–3936.
[5] Liu, Y., Zhang, J., Gao, H., Wang, Y., Liu, Q., Huang, S., Guo, C.F., and Ren, Z., 2017, Capillary-force-induced cold welding in silver-nanowire-based flexible transparent electrodes, Nano Lett., 17 (2), 1090–1096.
[6] Wang, R., and Ruan, H., 2016, Synthesis of copper nanowires and its application to the flexible transparent electrode, J. Alloys Compd., 656, 936–943.
[7] Mardiansyah, D., Triyana, K., and Harsojo, 2016, Effect of precursor molar ratio on the yield of Cu nanowires synthesized using aqueous solution method, Int. J. Adv. Sci. Eng. Inf. Technol., 6 (4), 447–450.
[8] Chu, H.C., Chang, Y.C., Lin, Y., Chang, S.H., Chang, W.C., Li, G.A., and Tuan, H.Y., 2016, Spray-deposited large-area copper nanowire transparent conductive electrodes and their uses for touch screen applications, ACS Appl. Mater. Interfaces, 8 (20), 13009–13017.
[9] Nam, V., and Lee, D., 2016, Copper nanowires and their applications for flexible, transparent conducting films: A review, Nanomaterials, 6 (3), E47.
[10] Hwang, H., Kim, A., Zhong, Z., Kwon, H., and Jeong, S., 2016, Reducible-shell-derived pure-copper-nanowire network and its application to transparent conducting electrodes, Adv. Funct. Mater., 26 (36), 6545–6554.
[11] Huang, W., Li, J., Han, F., Zhang, G., Suna, R., and Wong, C.P., 2017, Controllable synthesis and study on morphology of copper nanowires, J. Chin. Chem. Soc., 64 (11), 1354–1359.
[12] Mardiansyah, D., Triyana, K., Sosiati, H., and Harsojo, 2016, Synthesis of copper nanorods by aqueous solution method without heating external, AIP Conf. Proc., 1755 (1),150019.
[13] Tan, M.R., Donnabelle, M., and Balela, L., 2017, Electrochemical investigation of the growth of copper nanowires in the presence of ethylenediamine through mixed potential, J. Electrochem. Soc., 164 (7), 386–393.
[14] Harsojo, Puspita, L.A., Mardiansyah, D., Roto, R., and Triyana, K., 2017, The roles of hydrazine and ethylene diamine in wet synthesis of Cu nano wire, Indones. J. Chem., 17 (1), 43–48.
[15] Rathmell, A.R., Bergin, S.M., Hua, Y.L., Li, Z.Y., and Wiley, B.J., 2010, The growth mechanism of copper nanowires and their properties in flexible, transparent conducting films, Adv. Mater., 22 (32), 3558–3563.
DOI: https://doi.org/10.22146/ijc.30985
Article Metrics
Abstract views : 3938 | views : 2487Copyright (c) 2018 Indonesian Journal of Chemistry
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.
View The Statistics of Indones. J. Chem.