C Dots Derived from Waste of Biomass and Their Photocatalytic Activities

https://doi.org/10.22146/ijc.26652

Haryadi Haryadi(1*), Muhammad Ridwhan Wira Purnama(2), Ari Wibowo(3)

(1) Department of Chemical Engineering, Politeknik Negeri Bandung, Jl. Gegerkalong Hilir, Ds. Ciwaruga, Bandung 40559, West Java, Indonesia
(2) Department of Chemical Engineering, Politeknik Negeri Bandung, Jl. Gegerkalong Hilir, Ds. Ciwaruga, Bandung 40559, West Java, Indonesia
(3) Department of Chemical Engineering, Politeknik Negeri Bandung, Jl. Gegerkalong Hilir, Ds. Ciwaruga, Bandung 40559, West Java, Indonesia
(*) Corresponding Author

Abstract


Carbon nanodots (CNDs) which are part family of carbon nanoparticles have drawn a lot of attention due to their prominent characters and wide prospective applications. The materials are non-toxic and exhibit fluorescence properties that are potential for application in photocatalysis, optoelectronic, bioimaging and sensors. Various approaches of CNDs synthesis have been investigated by means of a large variety of starting materials and techniques. A green and an effective approach in gaining CNDs from wastes biomass-carbonaceous particles of a dried solid waste of cow manure have been employed by hydrothermal treatment. The CNDs were then attained after carbonaceous particles dissolution step under microwave irradiation. The temperature range of hydrothermal treatment was in between 250 to 300 °C. The formation of C=C, C-O bonds, and conjugated structures has been observed by FTIR and photoluminescence properties have been identified under 366 nm of UV irradiation. Furthermore, the morphology of as-synthesized CNDs was investigated by HR-TEM and crystallinity was observed by X-Ray Diffraction (XRD). Photocatalytic degradation of synthetic dye solution of methylene blue (MB) in the presence of carbon dots has been investigated under visible light.


Keywords


carbon nanodots; photocatalyst; methylene blue

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References

[1] Xu, X., Ray, R., Gu, Y., Ploehn, H.J., Geaheart, L., Raker, K., and Scrivens, W.A., 2004, Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments, J. Am. Chem. Soc., 126 (40), 12736–12737.

[2] Li, H., Kang, Z., Liu, Y., and Lee, S.T., 2012, Carbon nanodots: Synthesis, properties and applications, J. Mater. Chem., 22 (46), 24230–24253.

[3] Sahu, S., Behera, B., Maiti, T.K., and Mohapatra, S., 2012, Simple one-step synthesis of highly luminescent carbon dots from orange juice: Application as excellent bio-imaging agents, Chem. Commun., 48 (70), 8835–8837.

[4] Ray, S.C, Saha, A., Jana, N.R., and Sarkar, R., 2009, Fluorescent carbon nanoparticles: synthesis, characterization, and bioimaging application, J. Phys. Chem. C, 113 (43), 18546–18551.

[5] De, B., and Karak, N., 2013, A green and facile approach for the synthesis of water-soluble fluorescent carbon dots from banana juice, RSC Adv., 3 (22), 8286–8290.

[6] De, B., and Karak, N., 2013, A green and facile approach for the synthesis of water soluble fluorescent carbon dots from banana juice, RSC Adv., 3 (22), 8286–8290.

[7] Zuo, J., Jiang, T., Zhao, X., Xiong, X., Xiao, S., and Zhu, Z., 2015, Preparation and application of fluorescent carbon dots, J. Nanomater., 2015, 787862.

[8] Lu, Y.C., Chen, J., Wang, A.J., Bao, N., Feng, J.J., Wang, W., and Shao, L., 2015, Facile synthesis of oxygen and sulfur co-doped graphitic carbon nitride fluorescent quantum dots and their application for mercury(II) detection and bioimaging, J. Mater. Chem. C, 3 (1), 73–78.

[9] Srivastava, S., and Gajbhiye, N.S., 2011, Carbogenic nanodots: Photoluminescence and room-temperature ferromagnetism, ChemPhysChem, 12 (14), 2624–2632.

[10] Krysmann, M.J., Kelarakis, A., Dallas, P., and Giannelis, E.P., 2012, Formation mechanism of carbogenic nanoparticles with dual photoluminescence emission, J. Am. Chem. Soc., 134 (2), 747–750.

[11] Baker, S.N., and Baker, G.A., 2010, Luminescent carbon nanodots: Emergent nano lights, Angew. Chem. Int. Ed., 99, 6726–6744.

[12] Aji, M.P., Wiguna, P.A., Suciningtyas, S.A., Susanto, Rosita, N., and Sulhadi, 2016, Carbon nanodots from frying oil as a catalyst for photocatalytic degradation of methylene blue assisted solar light irradiation, Am. J. Appl. Sci., 13 (4), 432–438.

[13] Hu, B., Wang, K., Wu, L., Yu, S.H., Antonietti, M., and Titirici, M.M., 2010, Engineering carbon materials from the hydrothermal carbonization process of biomass, Adv. Mater., 22 (7), 813–828.

[14] Yin, B., Deng, J., Peng, X., Long, Q., Zhao, J., Lu, Q., Chen, Q., Li, H., Tang, H., Zhang, Y., and Yao, S., 2013, Green synthesis of carbon dots with down- and up-conversion fluorescent properties for sensitive detection of hypochlorite with a dual-readout assay, Analyst, 138 (21), 6551–6557.

[15] Georgakilas, V., Perman, J.A., Tucek, J., and Zboril, R., 2015, Broad family of carbon nanoallotropes: Classification, chemistry, and applications of fullerenes, carbon dots, nanotubes, graphene, nanodiamonds, and combined superstructures, Chem. Rev., 115 (11), 4744–4822.

[16] Tripathi, K.M., Tyagi, A., Ashfaq, M., and Gupta, R.K., 2106, Temperature-dependent, shape variant synthesis of photoluminescent and biocompatible carbon nanostructures from almond husk for applications in dye removal, RSC Adv., 6 (35) 29545–29553.

[17] Fragoso, C.T., Battisti, R., Miranda, C., and de Jesus, P.C., 2009, Kinetic of the degradation of C.I. Food Yellow 3 and C.I. Food Yellow 4 azo dyes by the oxidation with hydrogen peroxide, J. Mol. Catal. A: Chem., 301 (1-2), 93–97.

[18] Park, S.Y., Lee, H.U., Park, E.S., Lee, S.C., Lee, J.W., Jeong, S.W., Kim, C.H., Lee, Y.C., Huh, Y.S., and Lee, J., 2014, Photoluminescent green carbon nanodots from food-waste-derived sources: Large-scale synthesis, properties, and biomedical applications, ACS Appl. Mater. Interfaces, 6 (5), 3365–3370.



DOI: https://doi.org/10.22146/ijc.26652

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