Bulk Polymerization Kinetics of Hydroxy Terminated Polybutadiene and Toluene Diisocyanate with Infrared Spectroscopy
Heri Budi Wibowo(1*), Widhi Cahyo(2), Ratih Sanggra(3)
(1) Indonesian National Institute of Aeronautics and Space - LAPAN, Jl. Pemuda Persil No. 1, Jakarta 13220, Indonesia
(2) Indonesian National Institute of Aeronautics and Space - LAPAN, Jl. Pemuda Persil No. 1, Jakarta 13220, Indonesia
(3) Faculty of Engineering, Universitas Gadjah Mada, Jl. Grafika No. 2 Kampus UGM, Yogyakarta 55281, Indonesia
(*) Corresponding Author
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[1] Mahanta, A.K., and Pathak, D.D., 2012, “HTPB-Polyurethane: A Versatile Fuel Binder for Composite Solid Propellant” in Polyurethane, Eds. Zafar, F. and Sharmin, E., IntechOpen, Rijeka, Croatia, 229–262.
[2] Shokry, S.A., El Morsi, A.K., Sabaa, M.S., Mohamed, R.R., and El Sorogy, H.E., 2015, Synthesis and characterization of polyurethane based on hydroxyl terminated polybutadiene and reinforced by carbon nanotubes, Egypt. J. Pet., 24 (2), 145–154.
[3] Lee, S., Choi, C.H., Hong, I.K., and Lee, J.W., 2015, Polyurethane curing kinetics for polymer bonded explosives: HTPB/IPDI binder, Korean J. Chem. Eng., 32 (8), 1701–1706.
[4] Restasari, A., Ardianingsih, R., Abdillah, L., and Hartaya, K., 2015, Effects of Toluene Diisocyanate’s Chemical Structure On Polyurethane's Viscosity and Mechanical Properties for Propellant, Proceedings of International Seminar on Aerospace Science and Technology III, LAPAN, Jakarta, Indonesia, 59–67.
[5] Wibowo, H.B., 2015, Pengaruh gugus hidroksil sekunder terhadap sifat mekanik poliuretan berbasis HTPB (Hydroxy Terminated Polybutadiene), Jurnal Teknologi Dirgantara, 13 (2), 103–112.
[6] Wibowo, H.B., and Wibowo, R., 2016, Non Energetic Binder Application for RDBP Propellant Based Large Caliber Munition (MKB), Proceedings of International Seminar on Aerospace Science and Technology IV, LAPAN, Jakarta, Indonesia, 82–91.
[7] Chen, C.Y., Wang, X.F., Gao, L.L., and Zheng, Y.F., 2013, Effect of HTPB with different molecular weights on curing kinetics of HTPB/TDI system, Chin. J. Energetic Mater., 21 (6), 771–776.
[8] Chen, J.K., and Brill, T.B., 1991, Chemistry and kinetics of hydroxyl-terminated polybutadiene (HTPB) and diisocyanate-HTPB polymers during slow decomposition and combustion-like conditions, Combust. Flame, 87 (3), 217–232.
[9] Bina, C.K., Kannan, K.G., and Ninan, K.N., 2004, DSC study on the effect of isocyanates and catalysts on the HTPB cure reaction, J. Therm. Anal. Calorim., 78 (3), 753–760.
[10] Lee, S., Hong, I.K., Lee, J.W., and Jeong, W.B., 2014, Rheology and curing of hydroxyl terminated polybutadiene/(sugar or calcium carbonate) suspension, Polym. Korea, 38 (4), 417–424.
[11] Zhou, X., Chen, H., Chen, Q., and Ling, Q., 2017, Synthesis and characterization of two-component acidic ion intercalated layered double hydroxide and its use as a nanoflame-retardant in ethylene vinyl acetate copolymer (EVA), RSC Adv., 7 (84), 53064–53075.
[12] Dubois, C., Désilets, S., Ait‐Kadi, A., and Tanguy, P., 1995, Bulk polymerization of hydroxyl terminated polybutadiene (HTPB) with tolylene diisocyanate (TDI): A kinetics study using 13C‐NMR spectroscopy, J. Appl. Polym. Sci., 58 (4), 827–834.
[13] Sultan, W., and Busnel, J.P., 2006, Kinetic study of polyurethane formation by using differential scanning calorimetry, J. Therm. Anal. Calorim., 83 (2), 355–359.
[14] Mahanta, A.K., Goyal, M., and Pathak, D.D., 2010, Rheokinetic analysis of hydroxy terminated polybutadiene based solid propellant slurry, E-J. Chem., 7 (1), 171–179.
[15] Ajithkumar, S., Kansara, S.S., and Patel, N.K., 1998, Kinetics of castor oil based polyol–toluene diisocyanate reactions, Eur. Polym. J., 34 (9), 1273–1276.
[16] Cuihua, L., Tao, L., Xiaozue, Z., Jianhong, L., Aimin, P., and Xuhui, C., 2016, In situ FT-IR spectroscopic studies of curing reaction of HTPB and TDI on solid surface, J. Shenzen Univ. Sci. Eng., 33 (5), 452–456.
[17] Fiayyaz, M., Zia, K.M., Zuber, M., Jamil, T., Khosa, M.K., and Jamal, M.A., 2014, Synthesis and characterization of polyurethane/bentonite nanoclay based nanocomposites using toluene diisocyanate, Korean J. Chem. Eng., 31 (4), 644–649.
[18] Lucio, B., and de la Fuente, J.L., 2014, Rheokinetic analysis on the formation of metallo-polyurethanes based on hydroxyl-terminated polybutadiene, Eur. Polym. J., 50 (1), 117–126.
[19] Wibowo, H.B., 2016, Isomerisasi polimer melalui reaksi sain sayef untuk mengubah konfigurasi HTPB (hydroxyl terminated polybutadiene), Jurnal Teknologi Dirgantara, 14 (2), 137–146.
[20] Flory, P.J., 1953, Principles of Polymer Chemistry, Cornell University Press, Ithaca, United States.
[21] Toosi, F.S., Shahidzadeh, M., and Ramezanzadeh, B., 2015, An investigation of the effects of pre-polymer functionality on the curing behavior and mechanical properties of HTPB-based polyurethane, J. Ind. Eng. Chem., 24, 166–173.
[22] Krishnan, P.S.G., Ayyaswamy, K., and Nayak, S.K., 2013, Hydroxy terminated polybutadiene: Chemical modifications and applications, J. Macromol. Sci. Part A Pure Appl. Chem., 50 (1), 128–138.
[23] Navarchian, A.H., Picchioni, F., and Janssen, L.P.B.M., 2005, Rheokinetics and effect of shear rate on the kinetics of linear polyurethane formation, Polym. Eng. Sci., 45 (3), 279–287.
[24] Maurya, S.D., Purushothaman, M., Krishnan, P.S.G., and Nayak, S.K., 2014, Effect of nano-calcium carbonate content on the properties of poly(urethane methacrylate) nanocomposites, J. Thermoplast. Compos. Mater., 27 (12), 1711–1727.
[25] Villar, L.D., Cicaglioni, T., Diniz, M.F., Takahashi, M.F.K., and Rezende, L.C., 2011, Thermal aging of HTPB/IPDI-based polyurethane as a function of NCO/OH ratio, Mater. Res., 14 (3), 372–375.
[26] Wibowo, H.B., 2015, Pemisahan polimer HTPB (hydroxy terminated polybutadiene) melalui kolom resin berpori untuk merubah distribusi berat molekul HTPB, Jurnal Teknologi Dirgantara, 13 (1), 25–38.
DOI: https://doi.org/10.22146/ijc.24807
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