ISOLATION AND IDENTIFICATION OF MAIN AND SIDE PRODUCTS FROM ADDITION REACTION OF CARYOPHYLLENE OXIDE BY FORMIC ACID
M Muchalal(1*), Trisulistyaningsih Rahayu(2)
(1) Chemistry Department, Faculty of Mathematics and Natural Sciences Gadjah Mada University, Yogyakarta
(2) Chemistry Department, Faculty of Mathematics and Natural Sciences Gadjah Mada University, Yogyakarta
(*) Corresponding Author
Abstract
Main and side products from reaction of caryophyllene oxide and formic acid have been isolated using column chromatography with silica gel 60 G as stationary phase and n-hexane : ethyl acetat (9:1, v/v) as mobile phase. The first and second fraction were analyzed using infrared spectrophotometer, gas chromatography, and gas chromatography-mass spectrometer. Caryophyllene formiate as a main product was found in the first fraction. The side product that had been identified were 4,10,10-trimethyl-7-methylenebicyclo[6,2,0]decane-4-carbaldehyde, 2-(9-hydroxy-4,4,8 trimethyltricyclo[6,3,1,01,5]dodecyl)metanoate, clovanediol,4,11,11-trimethyl-8 methylene-3-bicyclo-[7,2,0]-undecen-5-ol,2,5-(6,10,10 imethyltricyclo[7,2,1,01,9]dodecyl)metanedioat, and derivative of caryophylleneformiate.
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[1] Guenther, E., 1950, The Essential Oils, diterjemahkan oleh S. Ketaren, 1990, Minyak Atsiri, jilid IV A, UI Press, Jakarta.
[2] Yang, X., C. Lederer, M. McDaniel, and M. Deinzer, 1993, J. Agric. Food. Chem, 41, 2082-2085.
[3] Wibowo, F.R., 2000, Hidrasi dan Adisi Metanol pada β-Kariofilena, Tesis, Program Pasca Sarjana UGM, Yogyakarta.
[4] Yang, X., and M. Deinzer, 1994, J. Nat. Prod. 57, 4, 514-517.
[5] Arata, K., K. Hayano and H. Shirahama, 1993, Bull. Chem. Soc. Japan, 66,218-223.
DOI: https://doi.org/10.22146/ijc.21910
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