THE STABILIZING OF ANATASE AEROGEL AT HIGH TEMPERATURE

https://doi.org/10.22146/ijc.21863

Silvester Tursiloadi(1*), Hiroshi Hirashima(2)

(1) Research Center for Chemistry, Indonesian Institute of Sciences, Kawasan PUSPIPTEK, Serpong, Tangerang 15314
(2) Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1, Hiyoshi, Kohoku-Ku, Yokohama 223-8522
(*) Corresponding Author

Abstract


Stable anatase is attractive to its notable functions for photo catalysis and photon-electron transfer.   Stable anatase TiO­2 containing amorphous SiO2 aerogel was prepared by hydrolysis of Ti (OC3H7)4 and Si (OC3H7)4 in a 2-propanol solution with acid catalyst. The solvent in wet gels was supercritically extracted in CO2 at 60 oC and 22 Mpa. Thermal evolutions of the microstructure of the gels were evaluated by TGA-DTA, N2 adsorption and XRD. A stable anatase TiO2 containing amorphous SiO2 aerogel with a BET specific surface area of 365 m2/g and a total pore volume of 0.20 cm3/g was obtained as prepared condition. The anatase phase was stable after calcination up to 1000 oC, and BET specific surface area, total pore volume and average pore diameter did not change significantly after calcination up to 900 oC.


Keywords


Supercritical extraction; sol-gel; aerogel; stable anatase structure

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References

[1] Regan, B.O., and Graetzel, M., 1991 Nature, 6346, 353, 737.

[2] Linsebigler, A.L., Lu, G., and Yates, J.T., 1995 Chem. Rev., 95 ,735

[3] Sclafani, A., and Herrman, J.M., 1996 J. Mater. Res., 100, 13655.

[4] Kormann, C., Bahnemann, D.W., and Hoffmann, M.R., 1988, J. Phys. Chem., 92, 5196.

[5] Sumita, T., Otsuka, H. Kubota, H., Nagata, M., Honda, Y., Gawa, M., Tsurushima, T., and Sadoh, T., 1999, Phys. Res. 148, 758.

[6] Haerudin, H., Bertel, S. and Kramer, R., 1998, J Chem. Soc., Faraday Trans, 10, 94, 1481.

[7] Hirashima, H., Imai, H., and Balek, V.,2001, J. Non-Crystalline Solids, 285, 96.

[8] Suh, D.J., Park, T.J., Kim, J.H., and Kim, K.L. 1997, Chem. Mater. 9, 1903.

[9] Barret, E.P., Joyner, L.G., and Halenda, P.H., 1951, J. Am. Chem. Soc., 73, 373

[10] Yusuf, M.M., Imai, H. and Hirashima, H., 2001, J. Non-Crystalline Solids, 285, 90.

[11]Imai, H., and Hirashima, H., 1999, J. Am. Ceram., Soc., 9, 82, 2301.



DOI: https://doi.org/10.22146/ijc.21863

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