A TRITERPENOID SAPONIN FROM SEEDS OF KOLOWE (Chydenanthus excelsus)

https://doi.org/10.22146/ijc.21854

Laode Rijai(1*), Supriyatna Sutardjo(2), Husein Hernandi Bahti(3), Unang Supratman(4), Rymond J. Rumampuk(5), W.C. Taylor(6)

(1) Chemistry Department, University of Mulawarman, Samarinda, East Kalimantan
(2) Pharmacy Departmennt, University of Padjadjaran, Bandung, West Java
(3) Chemistry Department, Univeristy of Padjadjaran, Bandung, West Java
(4) Chemistry Department, Univeristy of Padjadjaran, Bandung, West Java
(5) Chemistry Department, Universitas Negeri Manado, Tondano-Minahasa, Sulawesi Utara
(6) School of Chemistry, Univeristy of Sydney
(*) Corresponding Author

Abstract


A triterpenoid saponin have been isolated from n-butanol fraction of the seeds of kolowe (Chydenanthus excelsus). The structure was determined as 3-O-[β-D-glucopyranosyl(13)-β-D-xylopyranosyl(13)- β - D-glucuronopyranosyloxy]- 22α -O-(2-methylbutiroyloxyolean-12-en-15α,16α,28-tri-hydroxy. Structure elucidation was accomplished by NMR (HMBC, HMQC/HSQC, ROE, ROESY, TOCSY) methods, ESIMS, and IR spectroscopic.


Keywords


Chydenanthus excelsus; Lecythidaceae; Triterpenoid saponin

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References

[1] Dyuster, M., 1953, in Steeman dan Kruseman. Buletin, Organization for Scientific Research in Indonesia, 24, 105 – 110

[2] Rijai, L., Safitri, R., and Hanny, H., 2003 International Symposium on Biomedicines, Bogor Agriculture University, Indonesia. Proceeding, 25-29.

[3] Jiang, Z., Gallard, J.F., Adeline, M.T., Dumontet, V., Tri, M.V. and Pais, M., 1999, J. Nat. Prod.. 62, 62-876.

[4] Herlt, A. J., Mander, L.N., Pongoh, E., Rumampuk, R.J., and Tarigan, P., 2002, J. Nat. Prod. 65, 115 – 120.

[5] Higuchi, R., Komori, T. Kawasaki, T. and Lassak, E.V., 1983, Phytochemistry, 22, 5, 1235 – 1237.



DOI: https://doi.org/10.22146/ijc.21854

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Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

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