THE PREPARATION OF AN IODATE SELECTIVE ELECTRODE USING SILVER IODATE AS THE ACTIVE AGENT IN A CHITOSAN SUPPORT

https://doi.org/10.22146/ijc.21670

Ani Mulyasuryani(1*), Qonitah Fardiyah(2), Rizki Sugiri(3)

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Brawijaya University Jl. MT Haryono, Malang, Indonesia
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Brawijaya University Jl. MT Haryono, Malang, Indonesia
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Brawijaya University Jl. MT Haryono, Malang, Indonesia
(*) Corresponding Author

Abstract


The iodate-selective electrode based on the principle of precipitation reaction could be made by coating the platinum wire with silver iodate (AgIO3). In this research was carried out optimization the iodate-selective electrode using chitosan membrane as an AgIO3 support. The AgIO3 were added in the 2 mL 1% chitosan solution, is 0.5 to 2.5 % (w/v). The thickness of the membrane used is 6 to 12 µm. The electrode cell potential is measured against Ag/AgCl electrode as a reference electrode. The optimum electrode performance was at 2.0 % of AgIO3 with thickness a membrane of 10 µm. The iodate-selective electrode has a Nernstian factor is 52.96 mV/decade and a response time of 10 seconds. The concentration range was determined from 10-3 M to 10-1 M and the detection limit is 1.12 x 10-5 M.


Keywords


Ion Selective Electrode; Iodate; Chitosan Membrane

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References

[1] Mannar, M.G.V. and Dunn., T., 1995, Choice and Dosage of Iodine Compound for Salt Iodization, http://www.ajur.uni.edu

[2] Djokomoeldjanto, R., 1993, Hipotiroidi di Daerah Defisiensi Iodium, Kumpulan Naskah Simposium GAKI, Badan Penerbit Universitas Diponegoro, Semarang, 35-46.

[3] Muhilal, Jalal and Hardiansyah, 1998, Angka Kecukupan Gizi Rata-Rata yang Dianjurkan, Widyakarya Pangan dan Gizi Nasional VI, LIPI, Jakarta.

[4] Mulyasuryani, A., 2006, The Coated Wire Silver/Silver Iodate As An Ion Selective Iodate Electrode, The 2006 Seminar on Analytical Chemistry, Yogyakarta

[5] Oshita, K., Oshima, M., Gao, Y., Lee, K.H., Motomizu, Sh., 2002, Anal. Sci., 18, 1121 -1125.

[6] Rohindra, D.R., Nand, A.V., Khurma, J.R., 2005, Swelling Properties of Chitosan Hydrogel, Dept. Chem. Univ. South Pacific, Fiji.

[7] Pungor, E., 2001, Sensors, 1, 1 – 12

[8] Wang, J., 2001, Analytical Electrochemistry, 2rd ed., VCH Publisher, Inc., 133 – 160.

[9] Rundle, C.C, 2006, A Beginners Guide to Ion-Selective Electrode Measurements, Nico2000 Ltd, London, UK, http://www.studysphere.com/



DOI: https://doi.org/10.22146/ijc.21670

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Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

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