ADSORPTIVE REMOVAL OF HAZARDOUS INORGANIC ELEMENTS FROM WATER BY USING ORANGE WASTE

https://doi.org/10.22146/ijc.21581

Katsutoshi Inoue(1*)

(1) Department of Applied Chemistry, Saga University, Honjo-machi 1, Saga 840-8502
(*) Corresponding Author

Abstract


Pectic acid contained in some fruits like orange and apple is natural chelating polymeric material, exhibiting excellent adsorption behavior for some cationic metal ions including toxic heavy metals such as lead and copper. In addition, it also exhibits excellent adsorption behavior for some hazardous inorganic anionic species like phosphorus, arsenic and fluoride by loading some high valence cationic metal ions like zirconium(IV) in advance.For the practical application to the removal of these hazardous inorganic elements from various waste water at cheap cost, orange juice residue was employed instead of pure pectic acid. Orange juice residue just after juicing was activated by saponification with small amount of calcium hydroxide to prepare the sorbent.Some hazardous cationic species like lead(II), copper(II) and cadmium(II) were effectively adsorbed on this sorbent, while toxic anionic species like phosphate, arsenate, arsenite and fluoride were also effectively adsorbed on zirconium(IV)-loaded sorbent.


Keywords


Orange waste; Pectic acid; Natural chelating material; Heavy metals; Arsenic; Phosphorus; Adsorption; Removal; Water

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References

[1] Dhakal, R.P., Ghimire, K.N., Inoue, K., Yano, M., and Makino, K., 2005, Sep. Pur. Technol., 42, 219-225

[2] Yoshida, I., Ueno, K., and Kobayashi, H., 1978, Sep. Pur. Technol., 13, 173-184

[3] Takeswhita, R., Yoshida, I., and Ueno, K., 1979, Bull. Chem. Soc. Jpn., 52, 2577-2580

[4] Yoshida, I., Konomi, T., Shimonishi, Y., Morise, A., and Ueno, K., 1981, Nippon Kagakukaishi, (3), 379-384 (in Japanese)

[5] Dhakal, R.P., Ghimire, K.N., and Inoue, K., 2005, Hydrometallurgy, 79, 182-190

[6] Biswas, B.K., Inoue, J., Inoue, K., Ghimire, K.N., Harada, H., Ohto, K., and Kawakita, H., 2008, J.Hazard.Mater., 154, 1066-1074

[7] Biswas, B.K., Inoue, K., Ghimire, K.N., Ohta, S., Harada, H., Ohto, K., and Kawakita, H., 2007, J.Colloid Int.Sci., 312, 214-223

[8] Biswas, B.K., Ghimire, K.N., Inoue, K., Ohto, K., and Kawakita, H., 2007, J.Ion Exchange, 18, 428-433.

[9] Matsueda, M., Inoue, K. Harada, H., Ohto, K. Kawakita, H., 2008, Adsorptive removal of fluoride by zirconium(IV)-loaded orange juice residue, Preprint of 73rd Annual Meeting of the Society of Chemical Engineeres, Japan, S317, Hamamatsu, Mar.17-19, 2008.



DOI: https://doi.org/10.22146/ijc.21581

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Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

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