FABRICATION AND CHARACTERIZATION OF CARBON COMPOSITE FROM COCONUT SHELL CARBON

https://doi.org/10.22146/ijc.21398

Meytij Jeanne Rampe(1*), Bambang Setiaji(2), Wega Trisunaryanti(3), Triyono Triyono(4)

(1) Student of Doctorate Program, Department of Chemistry, Faculty of Mathematic and Natural Sciences, Universitas Gadjah Mada
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada Sekip Utara, Yogyakarta 55281
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada Sekip Utara, Yogyakarta 55281
(4) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada Sekip Utara, Yogyakarta 55281
(*) Corresponding Author

Abstract


Structure and chemical composition of coconut shell carbon with polyvinyl alcohol (PVA) as the stimulant through the observation of TG-DTA, SEM-EDS and FTIR has been studied. The process was carried out by calcining coconut shell charcoal at the temperature of 873 and 1023 K under Nitrogen flow, then mixed with polyvinyl alcohol (PVA) under composition of 2.5 to 7.5% (wt) in water solvent. The growing of carbon composite structure was observed by heating the samples in Argon gas of 1673 K, the rate of temperature was 10 K/min in 3 h. The products were then analyzed by TG-DTA, SEM-EDS, FTIR and XRD. The result showed that the products were in uniform particle sizes of micrometer dimensions and spherical particles shape, with average content of C element was 97.44% (wt), aromatic character and semi-crystalline structure.

Keywords


coconut shell carbon; PVA; carbon composite; TG/DTA; SEM/EDS; FTIR; XRD

Full Text:

Full Text PDF


References

[1] Lin, C.C., and Yen, C.C., 2007, J. Appl. Electrochem., 37, 7, 813–817.

[2] Inagaki, M., 2000, New Carbon: Control of Structure and Functions, Elsevier, Armsterdam.

[3] Buchman, A., and Bryant, R.G., 1999, Appl. Compos. Mater., 6, 5, 309–326.

[4] Hirose, T., Zhao, B., Okabe, T., and Yoshimura, M., 2002, J. Mater. Sci., 37, 16, 3453–3458.

[5] Sahajwalla, V.A.S., Mehta, A.S., and Khanna, R., 2004, Metall. Mater. Trans. B, 35, 1, 75–83.

[6] Elsayed, M.A., Hall, P.J., and Heslop, M.J., 2007, Adsorption, 13, 3-4, 299–306.

[7] Seok-Jin, S., Jung-Sik, C., Ko-Yeon, C., Sun-Day, S., Savithri, V., and Tae-Hwan, K., 2005, Korean J. Chem. Eng., 22, 2, 291–297.

[8] Tae-Hwan, K., Savithri, V., Seok-Jin, S., and Dong, K.J., 2002, J. Porous Mater., 9, 4, 279–286.

[9] Van der Marrel, H.W., and Beutelspacher, M.H., 1976, Atlas of Infrared Spectroscopy of Clay Minerals and Their Admixtures, Elsevier, New York.

[10] Ilcin, M., Hola, H., Bakajova, B., and Kucerik, J., 2010, J. Radioanal. Nucl. Chem., 283, 1, 9–13.

[11] Wiratmoko, A., and Halloran, J.W., 2009, J. Mater. Sci., 44, 8, 2097–2100.

[12] Rantitsch, G., Grogger, W., Teichert, C., Ebner, F., Hofer, C., and Maurer, E-M., 2004, Int. J. Earth Sci., 93, 6, 959–973.

[13] Fraga, M.A., Jordao, J., Mendes, M.J., Freitas, M.M.A., Faria, J.K., and Figueiredo, J.L., 2002, J. Catal., 209, 2, 355-364.

[14] Gupta, S., Sahajwalla, V., Burgo, J., Chaubal, P., and Youmans, T., 2005, Metall. Mater. Trans. B, 36, 3, 385–394.

[15] Miyazaki, K., Maskawa, N., Kobayashi, W., Kaku, M., Yasumaru, N., and Kiuchi, J., 2005, Appl. Phys. A, 80, 1, 17–21.

[16] Kang, L., Zhang, J., Lian, H. and Luo, M., 2007, Korean J. Chem. Eng., 24, 3, 508–511.

[17] Lalena, J.N., Cleary, D.A., Carpenter, E.E., and Dean, N.F., 2008, Inorganic Materials Synthesis and Fabrication, Wiley-Interscience, New York. 28–48.

[18] Mothe, C.G., and de Miranda, I.C., 2009, J. Therm. Anal. Calorim., 97, 2, 661–665.

[19] Mendez, S., and Santamaria, R., 2008, J. Mater. Sci., 43, 3, 906–921.

[20] Thomas, P.S., Guerbois, J.P., Russell, G.F., and Briscoe, B.J., 2001, J. Therm. Anal. Calorim., 64, 2, 501–508.

[21] Saito, Y., and Takanori, A., 2004, J. Wood Sci., 50, 1, 87–92.

[22] Rampe, M.J., Setiaji, B., Trisunaryanti, W., and Triyono, 2010, The Effect of Temperature on The Crystal Growth of Coconut Shell Carbon, Proceeding of the third International Conference on Mathematics and Natural Science (ICMNS), 23-25 November 2010, ITB Bandung, Indonesia.

[23] Yin, Y., Zhang, J., and Sheng, C., 2009, Korean J. Chem. Eng., 26, 3, 895–901.

[24] Rampe, M.J., Setiaji, B., Trisunaryanti, W., and Triyono., 2011, The Infrared Absorption change of Coconut Shell Carbon with Polyvinyl Alcohol Stimulant, Proceeding Conference on Materials, the 1st International Conference on Materials Engineering (ICME) and the 3rd AUN/SEED-Net Regional Conference on Materials (RCM), 2-3 February 2011. Yogyakarta, Indonesia. 153-158.

[25] Souza, B.S., Moreira, A.P.D., and Teixeira, A.M.R.F., 2009, J. Therm. Anal. Calorim., 97, 637–642.



DOI: https://doi.org/10.22146/ijc.21398

Article Metrics

Abstract views : 2976 | views : 3523


Copyright (c) 2011 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 


Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web
Analytics View The Statistics of Indones. J. Chem.