CARBON PASTE ELECTRODE HEXADECYLTRIMETHYLAMMONIUM BROMIDE MODIFIED NATURAL ZEOLITE FOR CHROMIUM(VI) DETECTION

https://doi.org/10.22146/ijc.21294

Budi Riza Putra(1), Latifah K Darusman(2*), Eti Rohaeti(3)

(1) Division of Analytical Chemistry, Department of Chemistry, Faculty of Mathematics and Natural Sciences, Bogor Agricultural University, Kampus IPB Darmaga, Bogor 16680
(2) Division of Analytical Chemistry, Department of Chemistry, Faculty of Mathematics and Natural Sciences, Bogor Agricultural University, Kampus IPB Darmaga, Bogor 16680
(3) Division of Analytical Chemistry, Department of Chemistry, Faculty of Mathematics and Natural Sciences, Bogor Agricultural University, Kampus IPB Darmaga, Bogor 16680
(*) Corresponding Author

Abstract


A simple voltammetric technique for quantification of chromium(VI) is presented in this work. The technique is based on linear sweep voltammetric reduction Cr(VI) on hexadecyltrimethylammonium bromide (HDTMABr) modified Lampung zeolite carbon paste electrode. Selected HDTMABr concentration for natural zeolite modification is obtained 200 mM. Working electrode for chromium(VI) detection is made by graphite, paraffin oil and HDTMABr modified Lampung zeolite. The effect of supporting electrolyte matrix, pH and also scan rate is also investigated. The calibration curve for chromium(VI) detection using the proposed method shows linearity from 0.2 to 1.0 mM with sensitivity, detection and quantification limit, and precision was 0.4294 mM, 3.63 x 10-4 mM, 1.197 x 10-3 mM, 4.49%, respectively.

Keywords


Lampung clinoptilolite zeolite; chromium(VI); HDTMABr modified zeolite carbon paste electrode; linear sweep voltammetry; heavy metal

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DOI: https://doi.org/10.22146/ijc.21294

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