TOTAL HYDROGENATION OF BIOMASS-DERIVED FURFURAL OVER RANEY NICKEL-CLAY NANOCOMPOSITE CATALYSTS

https://doi.org/10.22146/ijc.21291

Rodiansono Rodiansono(1*), Takayoshi Hara(2), Shogo Shimazu(3)

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Lambung Mangkurat, Jl. A. Yani Km 35.8 Banjarbaru South Kalimantan 70713
(2) Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Chiba, Jl. Yayoi-cho, Inage-ku, Chiba-shi, Chiba Japan 263-8522
(3) Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Chiba, Jl. Yayoi-cho, Inage-ku, Chiba-shi, Chiba Japan 263-8522
(*) Corresponding Author

Abstract


Inexpensive Raney Ni-clay composite (R-Ni/clay) catalysts exhibited excellent activity and reusability in the total hydrogenation of biomass-derived furfural into tetrahydrofurfuryl alcohol under mild conditions. For the Raney Ni-bentonite (R-Ni/BNT) catalysts, the complete reaction was achieved at 393 K, 180 min giving almost 99% yield of tetrahydrofurfuryl alcohol. The R-Ni/BNT catalyst was found to be reusable without any significant loss of activity and selectivity for at least six consecutive runs.

Keywords


Raney Ni; clay-composite; total hydrogenation; furfural; furfuryl alcohol; tetrahydrofurfuryl alcohol

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DOI: https://doi.org/10.22146/ijc.21291

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