Reduction of Aldehydes Using Sodium Borohydride under Ultrasonic Irradiation

https://doi.org/10.22146/ijc.21168

Maulidan Firdaus(1*), Nestri Handayani(2), Lina Tri Marfu’ah(3)

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sebelas Maret University, Jl. Ir. Sutami 36A Surakarta 57126
(2) Department of Pharmacy, Faculty of Mathematics and Natural Sciences, Sebelas Maret University, Jl. Ir. Sutami 36A Surakarta 57126
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sebelas Maret University, Jl. Ir. Sutami 36A Surakarta 57126
(*) Corresponding Author

Abstract


A simple, energy efficient, and relatively quick synthetic procedure for the reduction of aldehydes under ultrasonic irradiation is reported. Satisfactorily isolated yields (71-96%) were achieved confirming that the preparation of alcohol by aldehyde reduction is possible in green and sustainable fashion.

Keywords


green synthesis; ultrasound irradiation; aldehyde reduction; sodium borohydride

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References

[1] Paquette, L., 1995, Reagents for Organic Synthesis, Wiley, New York.

[2] Azizi, N., Batebi, E., Bagherpour, S., and Ghafuri, H., 2012, RSC Adv., 2 (6), 2289–2293.

[3] Cho, B.T., Kang, S.K., Kim, M.S., Ryu, S.R., and An, D.K., 2006, Tetrahedron, 62 (34), 8164–8168.

[4] Chandrasekhar, S., and Shrinidhi, A., 2014, Synth. Commun., 44 (14), 2051–2056.

[5] Kuroiwa, Y., Matsumura, S., and Toshima, K., 2008, Synlett, 16, 2523–2525.

[6] Brogan, A.P., Dickerson, T.J., and Janda, K.D., 2007, Chem. Commun., 46, 4952–4954.

[7] Kidwai, M., Bansal, V., Saxena, A., Shankar, R., and Mozumdar, S., 2006, Tetrahedron Lett., 47 (25), 4161–4165.

[8] Tanaka, K., and Toda, F., 2000, Chem. Rev., 100 (3), 1025–1074.

[9] Naik, R., Nizam, A., Siddekha, A., and Pasha, M.A., 2011, Ultrason. Sonochem., 18 (5), 1124–1127.

[10] Nikpassand, M., Fekri, L.Z., and Farokhian, P., 2016, Ultrason. Sonochem., 28, 341–345.

[11] Jumina, Siswanta, D., and Zulkarnain, A.K., 2001, Indones. J. Pharm., 12, 24–35.

[12] Zbancioc, G., Florea, O., Jones, P.G., and Mangalagiu, I.I., 2012, Ultrason. Sonochem., 19 (3), 399–403.

[13] Hallett, J.P., and Welton, T., 2011, Chem. Rev., 111 (5), 3508–3576.

[14] Budavari, S., 1989, The Merck index, an encyclopedia of chemicals, drugs, and biologicals, 11th Ed., John Wiley and Sons Inc., New York.

[15] Zeynizadeh, B., and Yahyaei, S., 2004, Z. Naturforsch, 59 (6), 704–710.

[16] Gupta, M.S., and Venkatachalam, V.V., 2006, Asian J. Chem., 18 (4), 2993–2996.

[17] Kim, I.S., Choi, D.K., and Jung, H.J., 2011, Molecules, 16 (7), 5349–5361.

[18] Jung, H.J., Song, Y.S., Lim, C.J., and Park, E.H., 2008, Arch. Pharmacal Res., 31 (10), 1275–1279.



DOI: https://doi.org/10.22146/ijc.21168

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